Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/16572
標題: 應用在染料敏化太陽能電池之鋅紫質合成
Synthesis of Zinc Porphyrins for Dye-Sensitized Solar Cells
作者: 李政緯
Lee, Cheng-Wei
關鍵字: porphyrin
紫質
solar
太陽電池
出版社: 化學系所
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摘要: 我們合成了這一系列將應用到太陽能電池上的色素,而這些色素我們是利用酸基與TiO2連結,同時我們將這個取代基放到紫質不同的位置上來探討之間的差異性。這些樣品的製備我們是利用Sonogashira cross-coupling(30a, 30b, 39, 41, 42, 44 和77)及Suzuki cross-coupling(28a和28b),而化合物33和38我們是利用與Zn3相似的方法,就是利用cyanoacetic acid來合成的。 化合物44我們得到較強的轉換率2.33%,而相較於化合物39大約提昇了66%。我們發現利用triarylamine來當作推電子基是可以有效的提升轉換率。我們相信以紫質為主體的色素會有更好的轉換效率被發現。
A series of novel zinc porphyrins were synthesized for use as photosensitizers in TiO2 dye-sensitized solar cells. The porphyrin sensitizers are attached to TiO2 by carboxylic acid group. The carboxylic acid group was placed on diffrernt substitution positions of the porphyrin core.The preparation of porphyrins 30a, 30b, 39, 41, 42, 44 and 77 with ethyne-linked functional groups can be achieved by the Sonogashira cross-coupling method, and 28a and 28b were prepared by the Suzuki cross-coupling reaction. The cyanoacetic acid derivatives 33 and 38 were prepared simlar to that of Zn3. The porphyrin sensitized TiO2 cell exhibited a power conversion efficiency of 2.33% (compound 44), which was improved by 66% relative to compound 39. We found a way to improve the power conversion efficiency of DSSCs by using triarylamine as an electron-donating group of porphyrin dyes. We believe that porphyrin-based DSSCs with even higher efficiency can be obtained.
URI: http://hdl.handle.net/11455/16572
其他識別: U0005-0608200709144000
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