Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/16688
標題: 應用在染料敏化太陽能電池之雙紫質的合成
Synthesis of Porphyrin Dimers for Dye-Sensitized Solar Cell
作者: 梁佑任
Liang, Yu-Jen
關鍵字: solar cell
太陽能電池
porphyrin dimers
雙紫質
出版社: 化學系所
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摘要: 我們成功的合成出利用meso-meso或β-β、meso-meso、β-β,直接連接兩個紫質的雙紫質染料,同時我們也合成出單一紫質染料,而合成出來的這些紫質染料則是透過羧酸基與TiO2連接,然後應用於太陽能電池上。這些染料的製備我們是利用Sonogashira cross-coupling與Suzuki cross-coupling反應來進行。 我們同時也在meso-位置引進推電子基的triarylamine或是diarylamine,希望對光電轉換率能有所提昇。另外就單一紫質方面,我們也將原本的benzoic acid換成Anthracene-9-carboxylic acid,從紫外-可見光光譜儀上可以看出其吸收範圍有明顯變寬的趨勢,因此對於光電轉換率應該也會有所提昇。 我們相信以紫質為主體的染料將會有越來越好的轉換效率。目前我們已合成出光電轉換率接近N3 dye的紫質染料,相信不久的將來會有所突破。
A serried of amino-substituted porphyrins and meso-meso, or β-β, meso-meso, β-β porphyrin dimers have been successfully synthesized. These porphyrin dyes are bonded to TiO2 through the carboxylic acid, and can be used in dye-sensitized solar cells. The preparation of these dyes with ethyne-linked functional groups can be achieved by the Sonogashira cross-coupling or Suzuki cross-coupling reaction. We introduced electron donating group, triarylamine or diarylamine, in meso-position of the porphyrin and expect that these porphyrins promote the photoelectric conversion efficiency. We believe that porphyrin-based DSSCs will be perform good conversion efficiency. We have synthesized the porphyrin dye 48, and its photoelectric conversion efficiency is close to that of N3 dye.
URI: http://hdl.handle.net/11455/16688
其他識別: U0005-2308200819051000
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