Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/16750
標題: 磁性奈米吸附劑結合實驗室閥系統之建立及其應用於環境中鉻物種分析
Development of Magnetic Nano-adsorbent Integrated with Lab-on-valve System for Chromium Speciation in the Environment Samples
作者: 陳俊豪
Chen, Chun-Hao
關鍵字: Cr(VI)
六價鉻
Cr(III)
chromium speciation
ICP-MS
三價鉻
物種分析
磁性奈米粒子
感應耦合電漿質譜儀
出版社: 化學系所
引用: (1) Barbato, J. L. K. a. J. In MLA Handbook for Writers of ResearchPapers. (2) Sueker, J. K.; Ph, D. R. D. M.; Brian, L. M. In Environmental Forensics; Academic Press: Burlington, 2005, pp 81-95. (3) Ghosh, D.; Bhattacharya, B.; Mukherjee, B.; Manna, B.; Sinha, M.; Chowdhury, J.; Chowdhury, S. The Journal of Nutritional Biochemistry 2002, 13, 690-697. (4) Caèmara, C.; Cornelis, R.; Quevauviller, P. TrAC Trends in Analytical Chemistry 2000, 19, 189-194. (5) Go´mez, V.; Callao, M. P. TrAC Trends in Analytical Chemistry2006, 25, 1006-1015. (6) Anderson, R. A. Regulatory Toxicology and Pharmacology 1997,26, S35-S41. (7) Anderson, R. A. Science of The Total Environment 1989, 86,75-81. (8) Anderson, R. A. J Am Coll Nutr 1998, 17, 548-555. (9) Anderson, R. Trace Elements in Human and Animal Nutrition:Orlando, 1986. (10) Trumbo, P.; Yates, A. A.; Schlicker, S.; Poos, M. Journal of the American Dietetic Association 2001, 101, 294-301. (11) Richard, F. C.; Bourg, A. C. M. Water Research 1991, 25,807-816. (12) 謝俊明勞工安全衛生研究季刊1995, 第三卷, 61-80. (13) OSHA, U. S. 2006. (14) 行政院環境保護署http://www.epa.gov.tw/ 1995. (15) Arslan, G.; Tor, A.; Cengeloglu, Y.; Ersoz, M. Journal of Hazardous Materials 2009, 165, 729-735. (16) Kalidhasan, S.; Ganesh, M.; Sricharan, S.; Rajesh, N. Journal of Hazardous Materials 2009, 165, 886-892. (17) Bittner, M.; Broekaert, J. A. C. Analytica Chimica Acta 1998,364, 31-40.75 (18) Derbyshire, M.; Lamberty, A.; Gardiner, P. H. E. AnalyticalChemistry 1999, 71, 4203-4207. (19) Collins, C. H.; Pezzin, S. r. H.; Rivera, J. F. L.; Bonato, P. S.;Windmo¨ller, C. u. C.; Archundia, C.; Collins, K. E. Journal ofChromatography A 1997, 789, 469-478. (20) Hagendorfer, H.; Goessler, W. Talanta 2008, 76, 656-661. (21) Foy, G. P.; Pacey, G. E. Talanta 2000, 51, 339-347. (22) Shi, Z.; Huang, X.; Cai, Y.; Tang, R.; Yang, D. Acta Biomaterialia 2009, 5, 338-345. (23) Ding, T.-H.; Lin, H.-H.; Whang, C.-W. Journal of Chromatography A 2005, 1062, 49-55. (24) Sperling, M.; Yin, X. F.; Welz, B. 1992; Royal Soc Chemistry;629-635. (25) Hassanien, M. M.; Kenawy, I. M.; El-Menshawy, A. M.; Ei-Asmy, A. A. Journal of Hazardous Materials 2008, 158, 170-176. (26) Gaspar, A.; Posta, J.; Sogor, C. Magyar Kemiai Folyoirat 1998,104, 153-164. (27) Sperling, M.; Xu, S.; Welz, B. Analytical Chemistry 1992, 64,3101-3108. (28) Liang, P.; Ding, Q.; Liu, Y. Journal of Separation Science 2006,29, 242-247. (29) Wang, J. H.; Hansen, E. H. Trac-Trend Anal Chem 2003, 22,225-231. (30) Hansen, E. H.; Miro, M. Trac-Trend Anal Chem 2007, 26, 18-26. (31) Wang, J. H.; Hansen, E. H. J Anal Atom Spectrom 2001, 16,1349-1355. (32) Wang, Y.; Chen, M. L.; Wang, J. H. J Anal Atom Spectrom 2006,21, 535-538. (33) Keith, L. H.; Gron, L. U.; Young, J. L. Chemical Reviews 2007,107, 2695-2708. (34) Klabunde, K. J. Nanoscale materials in chemistry; Wiley-Interscience: New York, 2001. (35) Tartaj, P.; Morales, M. D.; Veintemillas-Verdaguer, S.; Gonzalez-Carreno, T.; Serna, C. J. J. Phys. D-Appl. Phys. 2003,36, R182-R197.76 (36) 孫碧芸,聚乙烯亞胺(PEI)修飾之官能化磁性奈米吸附劑的製 備與應用於環境分析, 國立清華大學碩士論文,2008. (37) Ma, M.; Wu, Y.; Zhou, J.; Sun, Y.; Zhang, Y.; Gu, N. Journal ofMagnetism and Magnetic Materials 2004, 268, 33-39. (38) An-Hui Lu, E. S. F. S. h. Angewandte Chemie International Edition 2007, 46, 1222-1244. (39) Go´mez, V.; Callao, M. P. TrAC Trends in Analytical Chemistry 2006, 25, 1006-1015. (40) 行政院環境保護署環境檢驗所2006. (41) Jarvis, K. E.; Gray, A. L.; Houk, R. S. Handbook of inductively coupled plasma mass spectrometry; Chapman and Hall: New York, 1992. (42) Beauchemin, D. Anal. Chem. 2002, 74, 2873-2893. (43) Montaser, A. Inductively Coupled Plasma Mass Spectrometry;Wiley-VCH: New York, 1998. (44) Kahen, K.; Strubinger, A.; Chirinos, J. R.; Montaser, A.Spectrochimica Acta Part B: Atomic Spectroscopy 2003, 58, 397-413. (45) Giannenas, I.; Nisianakis, P.; Gavriil, A.; Kontopidis, G.;Kyriazakis, I. Food Chemistry 2009, 114, 706-711. (46) Lin, C. L.; Lee, C. F.; Chiu, W. Y. J Colloid Interf Sci 2005, 291,411-420. (47) Lee, P. L.; Sun, Y. C.; Ling, Y. C. J. Anal. At. Spectrom. 2009, 24,320-327. (48) Katsoyiannis, I. A.; Zouboulis, A. I. Water Research 2002, 36,5141-5155.
摘要: 自然界中鉻(Chromium)主要以三價鉻Cr(III)化合物及六價鉻Cr(VI)化合物的形式存在。Cr(III)為人體所需之微量元素之一,Cr(VI)則會對人體造成危害,鉻物種的分析因此成為重要的環境檢測課題。目前國內外常用之鉻物種分析方法,包括呈色法、螯合劑法、離子層析法等,再輔以光譜或質譜測定,方法偵測極限部分雖可低至sub-ppb等級,但仍需使用大量溶劑,不符合永續發展之理念。 本研究嘗試開發一新穎之磁性奈米吸附劑,結合實驗室閥系統(Lab-on-Valve,LOV)聯用感應耦合電漿質譜儀(ICP-MS),進行環境中Cr(III)及Cr(VI)之物種鑑定及定量。磁性奈米吸附劑具有外加磁場可操控性與高比表面積之特性,可提供簡化之前處理步驟與高吸附容量,表面修飾聚丙烯酸(Polyacrylic acid,PAA),羧酸基可提供選擇性陽離子交換,結果顯示可有效分離Cr(III)與Cr(VI)物種,Cr(III)偵測極限為0.7 μg L-1,Cr(VI)偵測極限為0.4 μg L-1,線性範圍為5-200 μg L-1,鉻物種分析於八分鐘以內完成,達到靈敏、快速、準確、簡便的Cr(III)及Cr(VI)物種分析,而降低溶劑使用量、使用再生性進料等優點,顯示出整合奈米技科,改善現有分析方法,達到綠色化學範疇,是具有可行性。
URI: http://hdl.handle.net/11455/16750
其他識別: U0005-2207200910173100
Appears in Collections:化學系所

文件中的檔案:

取得全文請前往華藝線上圖書館



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.