請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/16840
標題: Application of a nanoporous gold electrode with the highly morphological recoverability for non-enzymatic glucose sensing
高結構回復性的奈米孔洞金電極在非酵素葡萄糖感測之應用
作者: 林湘瑩
Lin, Hsiang-Ying
關鍵字: electrode
電極
glucose
non-enzymatic
葡萄糖
非酵素
出版社: 化學系所
引用: 1. 謝勝湖,糖尿病止步101關鍵,2007,星盒子出版 2. WHO, Fact sheet No. 312 in World health Organization, 2009 3. J. Wang, Chem. Rev., 2008, 108, 814 4. E. Katz, I. Willner, A. B. Kotlyar, J. Electroanal. Chem., 1999, 479, 64 5. S. Ben Aoun, Z. Dursun, T. Koga, G. S. Bang, T. Sotomura, I. Taniguchi, J. Electroanal. Chem., 2004, 567, 175 6. G. Reach, G. S. Wilson, Anal. Chem., 1992, 64, 381A 7. S. Updike, G. Hicks, Nature, 1967, 214, 986 8. H. R. Horton, L. A. Moran, R. S. Ochs, J. D. Rawn, K. G. Scrimgeour, Principle of Biochemistry, Third Edition, Prentice Hall, 2002. 9. P. Otero, M. Viana, E. Herrera, B. Boner, Free Radic. Res., 1997, 27, 619 10. P. A. Vaughan, D. L. Scott, J. F. McAleer, Anal. Chim. Acta, 1991, 248,361 11. K. K. Steward, A. Jain, K. K. Verma, Anal. Chim. Acta, 1992, 261, 261 12. J. J. O’Dea, J. Osteryoung, R. A. Osteryoung, Anal. Chem., 1981, 53, 695 13. D. J. Wiedemann, K. T. Kawagoe, R. T. Kennedy, E. L. Ciolkowski, R. Mark Wightman, Anal. Chem., 1991, 63, 2965 14. J. M. Zen, P. J. Chen, Anal. Chem. 1997, 69, 5087 15. J. M. Zen, C. T. Hsu, Y. L. Hsu, J. W. Sue, E. D. Conte, Anal. Chem. 2004, 76, 4251 16. A. Ciszewski, G. Milczarek, J. Electroanal. Chem., 1999, 469, 18 17. A. Vaškelis, E. Norkus, I. Stalnionien, G. Stalnionis, Electrochimica Acta, 2004, 49, 1613 18. C. F. Mai, C. H. Shue, Y. C. Yang, L. Y. Yang, S. L. Yau, K. Itaya, Langmuir, 2005, 21, 4964 19. G. Flatgen, S. Wasle, M. Lubke, C. Eickes, G. Radhakrishnan, K. Doblhofer, G. Ertl, Electrochimica Acta, 1999, 44, 4499 20. K. Charradi, C. Gondrana, A. B. H. Amara, V. Prvot , C. Moustyc, Electrochimica Acta, 2009, 54, 4237 21. A. Salimi, M. Mahdioun, A. Noorbakhsh, A. Abdolmaleki, R. Ghavami, Electrochimica Acta, 2011, 56 , 3387 22. S. J. Updike, G. P. Hicks, Nature, 1967, 214, 986 23. J. E. Frew, H. A. O. Hill, Anal. Chem., 1987, 59, 933A 24. R. Wilson, A. P. F. Turner, Biosens. Bioelectron.,1992, 7, 165 25. F. Kurniawan, V. Tsakova, V. M. Mirsky, Electroanalysis, 2006, 18,1937 26. Th. Wink, S. J. van Zuilen, A. Bult, W.P. van Bennekom, Analyst, 1997, 122, 43R 27. X. L. Luo, J. J. Xu, W. Zhao, H. Y. Chen, Sens. Actuators B, 2004, 97 ,249 28. H. Y. Wang, S. L. Mu, Sens. Actuators B, 1999, 56 ,22 29. H. Han, Y. Li, H. Yue, Z. D. Zhou, D. Xiao, M. M. F. Choi, Clin. Chim. Acta, 2008, 395, 155 30. X. F. Yang, Z. D. Zhou, D. Xiao, M. M. F. Choi, Biosens. Bioelectron. 2006, 21, 1613 31. Y. B. Vassilyev, O.A. Khazova, N. N. Nikolaeva, J. Electroanal. Chem., 1985, 196,105 32. R. Wilson, A. P. F. Turner, Biosens. Bioelectron.,1992, 7, 165 33. F. Shoji, M. S. Freund, J. Am. Chem. Soc.,2001, 123, 3383 34. S. Park, H. Boo, T. D. Chung, Anal. Chim. Acta, 2006, 556, 46 35. I. T. Bae, E. Yeager, X. Xing, C. C. Liu, J. Electroanal. Chem., 1991, 309, 131 36. M. W. Hsiao, R. R. Adzic, E. B. Yeager, Electrochim .Acta, 1992, 37, 357 37. M. W. Hsiao, R. R. Adzic, E. B. Yeager, J. Electrocheml. Soc., 1996, 143, 759 38. R. R. Adzic, M. W. Hsiao, E. B. Yeager, J. Electroanal. Chem., 1989, 260, 475 39. I. T. Bae, E. Yeager, X. Xing, C. C. Liu, Electroanal. Chem., 1991,309, 131 40. B. F. Beden, K. B. Largeaud, C. Kokoh, Electrochim. Acta , 1996, 41, 701 41. M. W. Hsiao, R. R. Adzic, E. B. Yeager, Electrochem. Soc., 1996, 143, 759 42. Y. Sun, H. Buck, T. E. Mallouk, Anal. Chem. , 2001, 73, 1599 43. E. Katz, I. Willner, J. Wang, Electroanalysis, 2004, 16, 19 44. S. Park, T. D. Chung, H. C. Kim, Anal. Chem., 2003, 75, 3046 45. T. G. S. Babu, T. Ramachandran, Electrochimica Acta, 2010, 55, 1612 46. Q. Chen, X. Shen, H. Gao, J. Colloid Interface Sci.,2007, 312, 272 47. J. C. Claussen, A. D. Fanklin, A. Haque, D. M. Porterfield, T. S. Fisher, ACS Nano, 2009, 1, 37 48. L. G. Yu, G. M. Zhang, Y. Wu, X. Bai, D. Z. Guo, J. Cryst. Growth, 2008, 310, 3125 49. Z. J. Zhuang, X. D. Su, H. Y. Yuan, Q. Sun, D. Xiao, M. M. F. Choi, Analyst, 2008, 133, 126 50. D. G. Wang, F. Guo, J. F. Chen, R. H. Zhao, Z. T. Zhang, Mater. Chem. Phys., 2008, 107, 426 51. J. Wang, D. F. Thomas, A. Chen, Anal.Chem., 2008, 80, 997 52. X. J. Zhang, G. F. Wang, X .W. Liu, J. J. Wu, M. Li, J. Gu, H. Liu, B. Fang, J. Phys. Chem. C, 2008, 112, 16845 53. X. L. Ren, D. Chen, X. W. Meng, F. Q. Tang, A. M. Du, L. Zhang, Colloids Surf. B, 2009, 72, 188 54. E. Pal, V. Hornok, A. Oszko, I. Dekany, Colloids Surf. A, 2009, 340, 1 55. M. Tominaga, T. Shimazoe, M. Nagashima, I. Taniguchi, Electrochem. Commun., 2005, 7, 189 56. Q. Xu, Y. Zhao, J. Z. Xu, J. J. Zhu, Sens. Actuators B: Chem.,2006, 114, 379 57. L. Q. Rong, C. Yang, Q. Y. Qian, X. H. Xia, Talanta, 2007, 72, 819 58. H. F. Cui, J. S. Ye, W. D. Zhang, C. M. Li, J. H. T. Luong, F. S. Sheu, Anal. Chim. Acta, 2007, 594, 175 59. P. Holt-Hindle, S. Nigro, M. Asmussen, A. C. Chen, Electrochem. Commun., 2008, 10, 1438 60. J. F. Huang, I. W. Sun, Adv. Funct. Mater., 2005, 15, 989. 61. A. J. Forty, Nature , 1979, 282, 597 62. J. F. Huang, Talanta , 2009, 77, 1694 63. S. Trasatti, O. A. Petrii, Pure Appl. Chem.,1991, 63, 711 64. B. Piela, P. K. Wroma, J. Electroanal. Chem., 1995, 388, 69 65. W. R. LaCourse, D. C. Johnson, Anal. Chem., 1993, 65, 50 66. L. A. Larew, D. C. Johnson, J. Electroanal. Chem., 1989, 262, 167 67. S. Cherevko, C. H. Chang, Sensors and Actuators B, 2009, 142 , 216 68. M. De Leo, A. Kuhn, Electroanalysis, 2007, 19, 227 69. J. Wang, Q. Chen, Anal. Chem., 1994, 66, 3600 70. J. Wang, G. Rivas, M. Chicharro, J. Electroanal. Chem., 1997, 439, 55 71. J. Yang, W. D. Zhang, S. Gunasekaran, Biosens. Bioelectron., 2010, 26, 279 72. L. M. Lu, L. Zhang, F. L. Qu, H. X. Lu, X. B. Zhang, Z. S. Wu, S. Y. Huan, Q. A. Wang, G. L. Shen, R. Q. Yu, Biosens. Bioelectron., 2009, 25, 218 73. J. H. Yuan, K. Wang, X. H. Xia, Adv. Funct. Mater., 2005, 15, 803 74. Y. Li, Y. Y. Song, C. Yang, X. H. Xia, Electrochem. Commun., 2007, 9, 981 75. Y. Bai, W. W. Yang, Y. Sun, C. Q. Sun, Sens. Actuators B, 2008, 134 , 471
摘要: In this study, an enzyme-free glucose sensor has been developed by using a nanoporous gold (NPG) electrode. The intrinsic ultra-high surface area also substantially enhances the sensitivity. Cyclic voltammetry (CV) and amperometric detection are used to investigate the electrochemical behavior of glucose. The long-term storability and the stability of the electrode are strongly demonstrated. Specifically, The CV of glucose on the NPG shows that the initial oxidation of glucose starts at -0.9V. The potential is more negative than -0.4 V on a smooth Au (SAu). The interested potential negative shift is related to the unique nano-structure on the NPG. The interferences from some common interfering species, such as ascorbic acid (AA), uric acid (UA), and p-acetaminophen (AP), are also successfully inhibited due to the intrinsic ultra-high surface area of NPG. The calibration curve shows a linear dependence in the glucose concentration range of 0.01-10.0 mM with an extra high sensitivity of 3769.6 µAmM−1 cm−2. The detection limit is 0.71 µM (signal-to-noise ratio of 3).
本研究主要目的在探討利用奈米孔洞金電極發展非酵素葡萄糖感測器。此電極具有極大的表面積可提高其靈敏度,可利用循環伏安法及安培法偵測以觀測葡萄糖的電化學行為。此電極更具有強效的長時間可儲存性及穩定性。 特別的是,在循環伏安圖中奈米孔洞金電極的葡萄糖氧化電位起始於-0.9V,比起市售的平面金電極電位往負向移動了-0.4V。電位向負的方向移動是由於奈米孔洞金電極上的獨特奈米結構所造成。由於奈米孔洞金電極具有極高的表面積可有效避免一般常見的干擾物種,例如:尿酸、抗壞血酸及乙醯氨酚等。利用奈米孔洞金電極製作出的檢量線可於葡萄糖濃度範圍為0.01mM至10mM呈現線性關係,並具有極高的靈敏度3769.6μAmM-1cm-2,其偵測極限為0.71µM(S/N=3)。
URI: http://hdl.handle.net/11455/16840
其他識別: U0005-0408201111424400
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-0408201111424400
顯示於類別:化學系所

文件中的檔案:
沒有與此文件相關的檔案。


在 DSpace 系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。