Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/17041
標題: Dynamical Behavior of Silver Atoms on the Si(111)-7x7 Surfaces
銀原子在矽(111)-7x7表面上的動態研究
作者: 蘇志川
Su, Chih-Chuan
關鍵字: STM
掃描穿隧顯微鏡
Si(111)
7x7
Silver
Dynamics
矽(111)

動態
出版社: 物理學系所
引用: [1] C. Julian Chen, Introduction to scanning tunneling microscopy. (Oxford University Press, New York, 1993). [2] The Official Web Site of the Nobel Foundation, Available at http://nobelprize.org/nobel_prizes/physics/laureates/1986/index.html. [3] Arthur Beiser, Concepts of modern physics, 6th ed. (McGraw-Hill, New York ; Boston, 2003). [4] Jenny Hoffman, Scanning Tunneling Microscopy, Available at http://hoffman.physics.harvard.edu/research/STMintro.php. [5] 羅榮立, "矽表面吸附粒子的辨識," 物理雙月刊 25 (5) (2003). [6] 黃至鵬, "運用掃描穿隧顯微術研究碳六十和碳八十四在矽(111)-7×7表面的吸附現象," 國立中興大學, 2004. [7] J. Neidhardt, H. Hogberg, and L. Hultman, "Arrhenius-type temperature dependence of the chemical desorption processes active during deposition of fullerene-like carbon nitride thin films," Surf. Sci. 569 (1-3), L289 (2004). [8] 許振嘉, 近代半導體材料的表面科學基礎. (北京大學出版社, 北京, 2002). [9] T. Jarolímek, J. Mysliveček, P. Sobotík et al., "Adsorption and diffusion of Ag atoms on Si(111)-(7×7) surface," Surf. Sci. 482-485, 386 (2001). [10] Rong-Li Lo, Mon-Shu Ho, Ing-Shouh Hwang et al., "Diffusion by bond hopping of hydrogen atoms on the Si(111)-7x7 surface," Phys. Rev. B 58 (15), 9867 (1998). [11] P. Sobotik, P. Kocan, and I. Ost''adal, "Direct observation of Ag intercell hopping on the Si(111)-(7×7) surface," Surf. Sci. 537, L442 (2003). [12] C. Zhang, G. Chen, K. D. Wang et al., "Experimental and theoretical investigation of single Cu, Ag, and Au atoms adsorbed on Si(111)-(7x7)," Phys. Rev. Lett. 94 (17) (2005). [13] 趙慶光, 溫度對反應速率之影響, Available at http://wwwdata.fy.edu.tw/env/html/08link/handout/pl015/default.htm, (2001). [14] Mark Winter, WebElements™ periodic table, Available at http://www.webelements.com/webelements/elements/text/Ag/enth.html.
摘要: 本文中將利用超高真空掃描探針顯微鏡研究關於銀原子吸附在矽(111)-7×7重構表面上的各種現象。首先觀察低蒸鍍量下銀原子在矽(111)-7×7重構表面上的吸附影像為一個較亮的三角形半單位晶格,當原子吸附在矽(111)-7×7 faulted半單位晶格中,三個角落上層原子會較亮,而吸附在unfaulted半單位晶格中時為三個中央上層原子較亮。接著藉由降低基板溫度至81K以降低銀原子在半單位晶格中跳動的速率,證實所觀測到的的確是單一銀原子吸附的情形,並且提出單一銀原子在半單位晶格中跳動機制的模型。接著觀察高溫(348K~398K)時,銀原子在矽(111)-7×7重構表面半單位晶格之間跳躍(jump)的動態研究。我們觀察到兩個銀原子跳到同一個半單位晶格中再分開的現象,也藉由Arrhenius equation證實所觀測到的銀原子並未產生鍵結,只是單純的跳躍到同一個半單位晶格中。最後則是利用高溫實驗中,在不同溫度下銀原子的跳動速率,搭配Arrhenius plot計算出單一銀原子跳出faulted半單位晶格的活化能Ea=0.93±0.04 eV、頻率係數Ra=1010.68±0.49 Hz;跳出unfaulted半單位晶格的活化能Ea=0.81±0.05 eV、頻率係數Ra=109.65±0.6 Hz。
The adsorption and the dynamics of silver atoms on the Si(111)- 77 surface were studied respectively using a variable temperature scanning probe microscope. Single silver atoms adsorbed on 77 unit cells to form bright triangles at room temperature. When a single silver atom adsorbed in a faulted half unit cell, three corner adatom looked brighter than usual. When it adsorbed in an unfaulted half unit cell, three center adatoms looked brighter than other adatoms. The dynamics of single silver atom hopping within a half unit cell were also studied at the temperature of 81K. A model regarding to a hopping mechanism for a single silver atom hopping within a faulted and an unfaulted half unit cell was proposed respectively. The dynamics of silver atoms jumping between different half unit cells was studied at temperatures between 348K~398K. A series of STM images revealed that two silver atoms sometimes jump into a same half unit cell. However, they never found to form a stable piece in our observation. The activation energies and pre-exponential factors for single silver atoms jumping out of faulted and out of unfaulted half unit cells were finally determined by Arrhenius plots.
URI: http://hdl.handle.net/11455/17041
其他識別: U0005-2208200716354400
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-2208200716354400
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