Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/2902
標題: 矽基染料敏化太陽能電池製備
Silicon based dye-sensitized solar cells
作者: 王郡瑩
Wang, Chun-Ying
關鍵字: 奈米結構電極
nanostructured electrode
染料敏化太陽能電池
金屬輔助矽蝕刻
dye-sensitized solar cell
electroless metal deposition
出版社: 機械工程學系所
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摘要: 本研究提出新式之染料敏化太陽能電池(DSSC)結構,以正向照光之方式取代傳統之背光輸入模式,其優點為不需背面透光故可使用非透明之光電極,且可以半導體材料光電極解決傳統之TCO導電玻璃經過高溫燒結後電阻增大的問題,提昇電子-電洞分離效果與光電轉換效能,電子由對電極經液態電解質中之I-/I3-氧化還原反應回到染料之方式運作。而以半導體材料為光電極亦有適合大面積生產之優點。 本研究提出以蝕刻反應製作之矽奈米柱陣列為基材,在不同的矽奈米柱基材上填充二氧化鈦奈米顆粒及染料,讓反應之後的光電子能迅速由矽奈米柱傳導出去,希望可以研發出效率更高之奈米結構染料敏化太陽能電池。並實際製作奈米結構電極DSSC 雛形版,以驗證新DSSC 架構之性能,實際光電流量測結果驗證雛形版之轉換效率已可達0.14%。
This study proposes a new dye-sensitized solar cells (DSSC) structure. In this new structure, top-side illumination is adopted to replace the traditional backlight input mode. An general electrode such as a semiconductor material can be used as the photoelectrode to replace the conventional implemented transparent conductive oxides (TCO) so that the high temperature sintering induced high resistance problem can be avoided. For the fabrication of the nano-structured photoelectrode, the electroless metal deposition (EMD) was utilized for the fabrication of nanorod array on the surface of silicon, followed by the dielectrophoretic deposition of TiO2 and then the coating of dye. The nanorod array enables a fast delivery of the photo-electrons to the connection wire. A prototype of the proposed novel DSSC was fabricated. The energy conversion efficiency was measured to be 0.14%.
URI: http://hdl.handle.net/11455/2902
其他識別: U0005-2307201216230300
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-2307201216230300
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