Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3199
標題: 含吡啶Benzoxazines之合成與性質研究
Synthesis and characterization of pyridine-containing benzoxazines.
作者: 施淯馨
Shih, Yu-Sin
關鍵字: 吡啶
pyridine
氧代氮代苯并環己烷
benzoxazine
出版社: 化學工程學系所
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摘要: 本論文使用含有吡啶結構之雙胺以一鍋法反應成功合成氧代氮代苯并環己烷(Benzoxazine)單體以及主鏈型Polybenzoxazine,所得化合物皆因含有吡啶結構使溶解度有不錯的表現。 將合成之單體由傅立葉轉換紅外線光譜鑑定可知有自催化之特性。而單體與樹脂進行共聚,以傅立葉轉換紅外線光譜儀觀察其變化可發現吡啶環可作為一反應點,使交聯度上升。所得固化物於熱性質部分皆有不錯的表現(Tg=209-224 oC)。 主鏈型Polybenzoxazine固化成膜後利用DMA、TMA、TGA等儀器檢測,具有好的熱性質(Tg=246-261 oC)、熱穩定性(Td5%=414- 418 oC)。 由質子酸進行質子化後Polybenzoxazine的光學性質表現可從紫外光-可見光於吸收光譜300-500 nm範圍及有強的螢光(570 nm)觀察而得。
In this thesis, the pyridine-containing diamines were used to synthesis the benzoxazine monomer and the main-chain polybenzoxazine, successfully in a one-pot procedure. The products achieved great solubility due to the pyridinic structure. The benzoxazine monomers possessed the self-catalytic effect determining by FT-IR and were further copolymerized with the epoxy resins and monitored by FT-IR spectra. We found that the pyridinic ring can be considered as a crosslinking site which resulted in the increase of the crosslinking density. Therefore, the cured products achieved great thermal properties (Tg = 209-224 oC). The main-chain polybenzoxazine films were characterized by DMA, TMA, and TGA. The films achieved great thermal properties (Tg = 246-261 oC), thermal stability ( Td5% = 414-419 oC). The optical properties of the protonated polybenzoxazine were obtained from UV-visible spectra. It exhibited an absorption band around 300-500 nm and possessed strong fluorescent at 570 nm.
URI: http://hdl.handle.net/11455/3199
其他識別: U0005-0108201315594900
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-0108201315594900
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