Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3257
標題: 製備高分子/植物廢棄物顆粒混合基材薄膜於陽離子染料的吸附應用
Preparation of Polymer/Plant Waste Particles Mixed Matrix Membranes for Adsorption of Cationic Dyes
作者: 林茄豪
Lin, Chia-Hao
關鍵字: 聚醚碸
Polyethersulfone
聚對苯二甲酸乙二酯
植物廢棄物顆粒
混合基材薄膜
陽離子染料
Polyethylene terephthalate
Plant waste particle
Mixed Matrix Membrane
Cationic dyes
出版社: 化學工程學系所
引用: 1.K. Mitrowska, A. Posyniak, J. Zmudzki, Determination of malachite green and leucomalachite green in carp muscle by liquid chromatography with visible and fluorescence detection, J. Chromatogr. A., 1089 (2005) 187. 2.X. Wu, G. Zhang, Y. Wu, X. Hou, Z. Yuan, Simultaneous determination of malacie green, gentian violet and their leuco-metabolites in aquatic products by high-performance liquid chromatography-linear ion trap mass spectrometry, J. Chromatogr. A., 1172 (2007) 121. 3.A. J. Chaudhary, B. Gangli, S. N. Grimes, The used of chromium waste sludge for the adsorption of color from dye effluent streams, J. Chem. Technol. Biotechnol., 77 (2002) 767. 4.S. Wang, Z. H. Zhu, A. Coomes, F. Haghseresht, G. Q. Lu, The physical and surface chemical characteristics of activated carbons and the adsorption of methylene blue from wastewater, J. Colloid Interface Sci., 284 (2005) 440. 5.R. Jiraratananon, A. Sungpet, P. Luangsowan, Performance evaluation of nanofiltration membranes for treatment of effluents containing reactive dye and salt, Desalination, 130 (2000) 177. 6.S. Karcher, A. Kornmuller, M. Jekel, Screening of commercial sorbents for the removal of reactive dyes, Dyes and Pigments, 51 (2001) 111. 7.I. Koyuncu, Reactive dye removal in dye/salt mixtures by nanofiltration membranes containing vinylsulphone dyes : effects of feed concentration and cross flow velocity, Desalination, 143 (2002) 243. 8.S. Netpradit, P. Thiravetyan, S. Towprayoon, Application of waste metal hydroxide sludge for adsorption of azo reactive dyes, Water Res., 37 (2003) 763. 9.C. Allegre, P. Moulin, M. Maisseu, F. Charbit, Treatment and reuse of reactive dyeing effluents, J. Mem. Sci., 269 (2006) 15. 10.E. N. E. Qada, S. J. Allen, G. M. Walker, Adsorption of basic dyes from aqueous solution onto activated carbons, Chem. Eng. J., 135 (2008) 174. 11.U. Kumar, M. Bandyopadhyay, Sorption of cadmium from aqueous solution using pretreated rice husk. Bioresour. Technol., 97 (2006) 104. 12.Z. Reddad, C. Gerente, Y. Andres, M. C. Ralet, J. F. Thibault, P. L. Cloirec, Ni(Ⅱ) and Cu(Ⅱ) binding properties of native and modified sugar beet pulp. Carbohydrate Polymers, 49 (2002) 23. 13.A. Saeed, M. W. Akhter, M. Iqbal, Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent. Sep. Purif. Technol., 45 (2005) 25. 14.B. H. Hameed, D. K. Mahmoud, A. L. Ahmad, Sorption of basic dye from aqueous solution by pomelo (Citrus grandis) peel in a batch system, Colloids and surfaces A: Physicochem. Eng. Aspects, 316 (2008) 78. 15.M. T. Uddin, M. A. Islam, S. Mahmud, M. Rukanuzzaman, Adsorptive removal of methylene blue by tea waste, J. Hazard. Mater., 164 (2009) 53. 16.G. Annadurai, R. S. Juang, D. J. Lee, Use of cellulose-based wastes for adsorption of dyes from aqueous solutions, J. Hazard. Mater., B92 (2002) 263. 17.Y. S. Ho, W. T. Chiu, C. C. Wang, Regression analysis for the sorption isotherms of basic dyes on sugarcane dust, Bioresour. Technol., 96 (2005) 1285. 18.M. A. M. Salleh, D. K. Mahmoud,W. A. W. A. Karim, A. Idris, Cationic and anionic dye adsorption by agricultural solid wastes : A comprehensive review, Desalination, 280 (2011) 1. 19.V. Vadivelan, K. V. Kumar, Equilibrium, kinetics, mechanism and process design for sorption of methylene blue onto rice husk, J. Colloid Interface Sci., 286 (2005) 90. 20.F. A. Pavan, A. C. Mazzocato, Y. Gushikem, Removal of methylene blue from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent, Bioresour. Technol., 99 (2008) 3162. 21.M. Dogan, H. Abak, M. Alkan, Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters, J. Hazard. Mater., 164 (2009) 172. 22.R. K. Xu, S. C. Xiao, J. H. Yuan, A. Z. Zhao, Adsorption of methyl violet from aqueous solutions by the biochars derived from crop residues, Bioresour. Technol., 102 (2011) 10293. 23.V. M. Vucurovic R. N. Razmovski, M. N. Tekic, Methylene blue (cationic dye) adsorption onto sugar beet pulp: Equilibrium isotherm and kinetic studies, J. Taiwan Inst. Chem. Eng., 43 (2012) 108. 24.賴怡伶, 含纖維素之生物吸附劑對重金屬吸附之研究, 碩士論文, 國立中央大學環境工程研究所, 桃園, 台灣 (2008). 25.邱永亮, 魏盛德, 染色化學, 徐氏基金會出版, 台北, 台灣 (1975). 26.劉家弘, 使用離子交換薄膜進行染料吸附/脫附之研究, 碩士論文, 國立中興大學化學工程研究所, 台中, 台灣 (2006). 27.吳政修, 使用陰離子交換薄膜從水中移除反應性染料之研究, 碩士論文, 國立中興大學化學工程研究所, 台中, 台灣 (2007). 28.J. K. Kapdan, F. Kargi, Simultaneous biodegradation and adsorption of textile dyestuff in an activated sludge unit, Process Biochem., 37 (2002) 973. 29.E. G. Solozhenko, N. M. Soboleva, V. V. Goncharuk, Decolourization of azodye solutions by Fenton’s oxidation. Water Res., 29 (1995) 2206. 30.M. Dogan, Y. Oademir, M. Alkan, Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite. Dyes Pigments, 75 (2007) 701. 31.W. A. ritschel, G. L. kearns, Handbook of Basic Pharmacokinetics : Including Clinical Applications 7th edition, American Pharmacists Association, Washington, USA (2009). 32.R. W. Sabnis, Handbook of biological dyes and stains : Synthesis and industrial applications, Wiley, New Jersey, USA (2010). 33.L. M. A. Fayoumi, M. A. Ezzedine, H. H. Akel, M. M. El Jamal, Kinetic Study of the Degradation of Crystal Violet by K2S2O8 Comparison with Malachite Green. Portugaliae Electrochim. Acta, 30 (2012) 121. 34.J. Cenes and R. A. Schoonheydt, Visible spectroscopy of methylene blue on hectorite laponite B, and barasym in aqueous suspension. Clays Clay Miner., 36 (1988) 214. 35.E. Q. Adams and L. Rosenstein, The color and ionization of crystal violet. J. Am. Chem. Soc., 36 (1914) 1452.
摘要: 本研究使用聚醚碸(polyethersulfone, PES)與聚對苯二甲酸乙二酯(polyethylene terephthalate, PET)為基材,摻混30 wt%的植物廢棄物顆粒(茶葉渣、香蕉皮、文旦皮與茭白筍殼,顆粒大小為45-100 μm),製備成具孔洞的混合基材薄膜(Mixed Matrix Membrane, MMM),孔洞大小為0.5-3 μm,水含量約為45-55%,離子交換容量為600-620 μmol/g membrane。所製備的混合基材薄膜應用於陽離子染料(甲烯藍、甲基紫)的吸附/脫附程序:溫度為室溫,pH值為 4。實驗結果得知:批次程序中8小時可達吸附平衡,甲烯藍的飽和吸附量為300-340 mg/g membrane,甲基紫為300-370 mg/g membrane。本研究並以80 %甲醇為溶劑之1 M KSCN(v/v)為脫附液,所得染料脫附率約95%。而在流動程序中,以流量1 mL/min進行吸附、清洗、脫附之循環,測試圓片薄膜模組的效率。以5 ppm為進料濃度,放入一片薄膜(bed volume = 0.07 mL),實驗結果得知:貫穿點為5-10 mL(70-140倍bed volume),染料吸附率與脫附率均約90%,且重覆三次的效果一致。 關鍵字:聚醚碸、聚對苯二甲酸乙二酯、植物廢棄物顆粒、混合基材薄膜、陽離子染料
In this study, a mixture of 30 wt% plant waste particles (e.g. tea leaves, banana peel, shaddock peel, and water bamboo husk) with polymer (e.g. polyethersulfone or polyethylene terephthalate) was blended to prepare the porous mixed matrix membranes (MMMs) for the removal of dyes from water. The plant waste particles had the diameter of 45-100 μm and zeta potential of banana peel and water bamboo husk were 1.5 and 2.5, the other particles(tea leaves and shaddock peel) were bring negative charge at any pH values. The prepared MMMs had the pore size of 0.5-3 μm, water content of 45-55%, and ion exchange capacity of 600-620 μmol/g membrane. The batch adsorption process of cationic dyes (methylene blue and methyl violet 2B) was conducted at room temperature and pH 4. The MMMs achieved an adsorption equilibrium after 8 hr, with the maximum adsorption capacities for methylene blue and methyl violet 2B at 300-340 mg/g membrane (1000-1130 mg/g particles) and 300-370 mg/g membrane (1000-1230 mg/g particles), respectively. In batch desorption, 1 N KSCN in 80% methanol was selected as the optimal desorption solution and the desorption efficiencies for MMMs were about 95%. In the flow process with 1 mL/min, the cycle of adsorption, washing, and elution was repeated to test the membrane efficiency. The loading dye concentration was 5 ppm, and one piece of MMM (bed volume of 0.07 mL) was placed in the 25 mm disc holder. The results showed that the breakthrough volumes were 5-10 mL (70-140 bed volume) and the ratios of adsorption and desorption were about 90%. The whole process could be repeated three times successfully, without any deterioration on the performance. Keyword:Polyethersulfone、Polyethylene terephthalate、Plant waste particle、Mixed Matrix Membrane、Cationic dyes.
URI: http://hdl.handle.net/11455/3257
其他識別: U0005-3007201310554000
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-3007201310554000
Appears in Collections:化學工程學系所

文件中的檔案:

取得全文請前往華藝線上圖書館

Show full item record
 
TAIR Related Article
 
Citations:


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.