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|標題:||An Efficient Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides|
sulfur bond formation
|摘要:||Commercially available Cu(2)O powder is a very reactive catalyst for the coupling of thiols to aryl iodides. A variety of functional groups including esters, unprotected amines, alcohols, and heterocycles tolerate the reaction conditions. Moreover, di-ortho-substituted aryl iodides with sterically demanding substrates were also coupled to give the desired aryl thioethers in good to excellent yields.|
|Appears in Collections:||化學系所|
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