Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/33894
標題: An Efficient Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides
作者: Kao, Hsin-Lun
Chen, Chin-Keng
Wang, Yu-Jen
Lee, Chin-Fa
關鍵字: Copper
Cross-coupling
Sulfur
Thioethers
Homogeneous catalysis
sulfur bond formation
c-s
nucleophilic-substitution
boronic acids
palladium
halides
ligand
arylation
complexes
oxide
摘要: Commercially available Cu(2)O powder is a very reactive catalyst for the coupling of thiols to aryl iodides. A variety of functional groups including esters, unprotected amines, alcohols, and heterocycles tolerate the reaction conditions. Moreover, di-ortho-substituted aryl iodides with sterically demanding substrates were also coupled to give the desired aryl thioethers in good to excellent yields.
URI: http://hdl.handle.net/11455/33894
ISSN: 1434-193X
Appears in Collections:化學系所

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