Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34386
DC FieldValueLanguage
dc.contributor.authorHong, F.E.en_US
dc.contributor.author林助傑zh_TW
dc.contributor.authorChang, Y.C.en_US
dc.contributor.authorChang, R.E.en_US
dc.contributor.authorLin, C.C.en_US
dc.contributor.authorWang, S.L.en_US
dc.contributor.authorLiao, F.L.en_US
dc.contributor.author洪豐裕zh_TW
dc.date1999zh_TW
dc.date.accessioned2014-06-06T07:47:38Z-
dc.date.available2014-06-06T07:47:38Z-
dc.identifier.issn0022-328Xzh_TW
dc.identifier.urihttp://hdl.handle.net/11455/34386-
dc.description.abstractUnder mild conditions, the reaction of Co-2(CO)(s) with HC=CSiMe3 in the presence of PPh(2)py gave a binuclear cobalt carbonyl complex, Co-2(CO)(4)(eta(2)-mu(2)-HC=CSiMe3)(mu-PPh(2)py) (1a), which has both zero-valent cobalt centers coordinated by a bidentate ligand, PPh(2)py. PPh(2)py is also an effective ligand in promoting the yield of 2,5-bis(trimethylsilanyl)cyclopenta-2,4-dien-1-one. A cobalt cluster complex, Co-4(CO)(10)(mu-P,N-PPh(2)py) (9) was obtained when two equivalents of Co-2(CO)(8) were reacted with PPh(2)py at a higher temperature. The phosphorus and nitrogen atoms of the ligand coordinate to cobalt in the basal and apical positions, respectively. These two compounds, la and 9 were characterized by spectroscopic means as well as X-ray crystal structure determination. (C) 1999 Elsevier Science S.A. All rights reserved.en_US
dc.language.isoen_USzh_TW
dc.relationJournal of Organometallic Chemistryen_US
dc.relation.ispartofseriesJournal of Organometallic Chemistry, Volume 588, Issue 2, Page(s) 160-166.en_US
dc.relation.urihttp://dx.doi.org/10.1016/s0022-328x(99)00368-xen_US
dc.subjectbidentate-liganden_US
dc.subjectmu-alkyne-bridgeden_US
dc.subjectbimetallic compondsen_US
dc.subjectcobalt clusteren_US
dc.subjectmolecular-structureen_US
dc.subjectbinuclear complexesen_US
dc.subject2-(diphenylphosphino)pyridineen_US
dc.subjectchemistryen_US
dc.subjectmolybdenumen_US
dc.subjecttungstenen_US
dc.titleDiphenyl-2-pyridylphosphine as a bidentate ligand in the coordination of dicobalt octacarbonyl; X-ray crystal structures of Co-2(CO)(4)(mu-P,N-PPh(2)py){mu-HC=CSiMe3}, and Co-4(CO)(10)(mu-P,N-PPh(2)py)en_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1016/s0022-328x(99)00368-xzh_TW
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