Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34534
標題: Preparation and characterization of a novel palladium complex: cis-dichloride(1,2-bis(diphenylphosphino)vinyi-P,P ',C)palladium(II)-(bis(diphenylphosphino)methane-P,P ')cobaltacarbonyl
作者: Chang, C.P.
洪豐裕
Hong, F.E.
關鍵字: palladium complex
cobalt complex
dppm
dppe
cross-coupling reactions
carbonyl-complexes
phosphine-ligands
crystal-structure
coordination
derivatives
acetylene
catalysts
chloride
solvate
期刊/報告no:: Journal of the Chinese Chemical Society, Volume 52, Issue 6, Page(s) 1105-1109.
摘要: A novel palladium complex 4, cis-dichloride(1,2-bis(diphenylphosphino)vinyl-P,P',C)palladium(II)-(bis(diphenylphosphino)methane-P,P')cobaltacarbonyl, was obtained and characterized from the treatment of [(mu-Ph2PCH2PPh2)Co-2(CO)(4)][(Ph2PC&3bond; CPPh2)-PdCl2] 3 with hydrochloric acid, The framework of 4 can be regarded as a grouping of two metal-containing fragments: -CO(CO)(2)(dppm) and PdCl2(mu-P,P-Ph2PCH = C(-)PPh2).
URI: http://hdl.handle.net/11455/34534
ISSN: 0009-4536
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