Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34670
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dc.contributor.authorWu, K.M.en_US
dc.contributor.author陳繼添zh_TW
dc.contributor.authorHuang, C.A.en_US
dc.contributor.authorPeng, K.F.en_US
dc.contributor.authorChen, C.T.en_US
dc.date2005zh_TW
dc.date.accessioned2014-06-06T07:48:07Z-
dc.date.available2014-06-06T07:48:07Z-
dc.identifier.issn0040-4020zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/34670-
dc.description.abstractThree pendant benzamidines [Ph-C(=NC6H5)-{NH(CH2)(2)NMe2}] (1), [Ph-C(=NC6H5)-{NH(CH2PY)}] (2) and [Ph-C (=NC6H5)-{NH(o-C6H4)(oxazoline)}] (3) are described. Reactions of 1, 2 or 3 with one molar equivalent of Pd(OAc)(2) in THF give the palladacyclic complexes [Ph-C{-NH(eta(1)-C6H4)} {=N(CH2)(2)NMe2}]Pd(OAc) (4), [Ph-C{NH(eta(1)-C6H4} {=N (CH2Py)}]Pd(OAc) (5) and [Ph-C{-NH(eta(1)-C6H4)} {=N(o-C6H4)(oxazoline)}]Pd(OAc) (6), respectively. Treatment of 4, 5 or 6 with excess of LiCl in chloroform affords [Ph-C{-NH(eta(1)-C6H4)} {=N(CH2)(2)NMe2}]PdCl (7), [Ph-C{-NH(eta(1)-C6H4} {=N(CH2Py}]PdCl (8) and [Ph-C{NH(eta(1)- C6H4)} {=N(o-C6H4)(oxazoline)}]PdCl (9). The crystal and molecular structures are reported for compounds 1, 3, 5, 6 and 7. The application of these palladacyclic complexes to the Suzuki and Heck coupling reactions was examined.(c) 2005 Elsevier Ltd. All rights reserved.en_US
dc.language.isoen_USzh_TW
dc.relationTetrahedronen_US
dc.relation.ispartofseriesTetrahedron, Volume 61, Issue 41, Page(s) 9679-9687.en_US
dc.relation.urihttp://dx.doi.org/10.1016/j.tet.2005.06.069en_US
dc.subjectpendant benzamidineen_US
dc.subjectpalladacyclic complexesen_US
dc.subjectoxazolineen_US
dc.subjectSuzukien_US
dc.subjectreactionen_US
dc.subjectHeck reactionen_US
dc.subjectpalladium(ii) complexesen_US
dc.subjectcoordination chemistryen_US
dc.subjectcrystal-structureen_US
dc.subjectpolymerization catalysisen_US
dc.subjectcyclometalated compoundsen_US
dc.subjectmolecular-structuresen_US
dc.subjectmagnesium complexesen_US
dc.subjectamine functionalityen_US
dc.subjectx-rayen_US
dc.subjectreactivityen_US
dc.titlePalladacycles bearing pendant benzamidinate ligands as catalysts for the Suzuki and Heck coupling reactionsen_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1016/j.tet.2005.06.069zh_TW
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