Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34692
標題: A simple method for the oxidation of primary alcohols with o-iodoxybenzoic acid (IBX) in the presence of acetic acid
作者: Lin, C.K.
陸大榮
Lu, T.J.
關鍵字: o-Iodoxybenzoic acid (IBX)
Oxidation
Aldehydes
hypervalent iodine reagents
manganese-dioxide oxidation
polymer-supported ibx
secondary alcohols
dimethyl-sulfoxide
carbonyl-compounds
organic-chemistry
mild oxidation
2-iodoxybenzoic
acid
selective oxidation
期刊/報告no:: Tetrahedron, Volume 66, Issue 51, Page(s) 9688-9693.
摘要: A simple method for the oxidation of primary alcohols to aldehydes using o-iodoxybenzoic acid (IBX) with the addition of stoichiometric acetic acid has been developed. Addition of acetic acid significantly accelerated the reaction rate. Under these conditions, primary aliphatic, benzylic, and allylic alcohols are smoothly converted to aldehydes in high yields (90-97%). (C) 2010 Elsevier Ltd. All rights reserved.
URI: http://hdl.handle.net/11455/34692
ISSN: 0040-4020
文章連結: http://dx.doi.org/10.1016/j.tet.2010.10.053
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