Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34966
標題: Dichloromethane activation. Direct methylenation of ketones and aldehydes with CH2Cl2 promoted by Mg/TiCl4/THF
作者: Yan, T.H.
楊圖信
Tsai, C.C.
Chien, C.T.
Cho, C.C.
Huang, P.C.
關鍵字: carbonyl-compounds
titanium
reduction
olefins
magnesium
esters
期刊/報告no:: Organic Letters, Volume 6, Issue 26, Page(s) 4961-4963.
摘要: This Mg-TiCl4-promoted CH2-transfer reaction of CH2Cl2 represents an extremely simple, practical, and efficient methylenation of a variety of ketones and aldehydes, especially in enolizable or sterically hindered ketones such as 2,2-dimethylcyclohexanone, camphor, and fenchone.
URI: http://hdl.handle.net/11455/34966
ISSN: 1523-7060
文章連結: http://dx.doi.org/10.1021/ol0478887
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