Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34970
標題: New, general, and practical enamine cyclopropanation using dichloromethane
作者: Tsai, C.C.
楊圖信
Hsieh, I.L.
Cheng, T.T.
Tsai, P.K.
Lin, K.W.
Yan, T.H.
關鍵字: metal carbene complexes
vinyl ethers
belactosin-a
olefins
methylenation
alkenes
derivatives
aldehydes
ketones
期刊/報告no:: Organic Letters, Volume 8, Issue 11, Page(s) 2261-2263.
摘要: Dichloromethane serves as a novel electrophilic carbene equivalent which adds to an enamine double bond. The presence of other alkene moieties in the enamine partner is well tolerated. Even enamines derived from sterically hindered ketones react readily with dichloromethane promoted by TiCl4-Mg.
URI: http://hdl.handle.net/11455/34970
ISSN: 1523-7060
文章連結: http://dx.doi.org/10.1021/ol0604365
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