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dc.contributorPo-Ching Wuen_US
dc.contributorTse-Min Chenen_US
dc.contributor.advisorChia-Chung Chenen_US
dc.contributor.authorChen, Jiun-Yuanen_US
dc.identifier.citation1. 王一雄。1996。土壤環境污染與農藥。初版。台北。明文。 2. 行政院農業委員會。1997。加保利 (Carbaryl) 農藥有效成分檢驗方法。編號:加保利 C1-0003-1.0。行政院農業委員會86農糧字第86116775A號公告。 3. 行政院農業委員會。1997。加保扶 (Carbofuran) 農藥有效成分檢驗方法。編號:I024。行政院農業委員會86農糧字第86116775A號公告。 4. 葉枚耕。1986。農藥生化學。初版。台北。國立編譯館。 5. 彭圖治、楊麗菊。1999。生命科學中的電分析化學。中國杭州。杭州大學出版社。 6. 詹博淵。1999。超微量農藥電化學分析。博士論文。台北:淡江大學化學學系研究所。 7. Besombes, Jean-Luc, Serge Cosnier, Pierre Labbe, and Gilbert Reverdy. 1994. A biosensor as warning device for the detection of cyanide, chlorophenols, atrazine and carbamate pesticides. Anal. Chim. Acta. 311:255. 8. Guiberteau A., T. Galeano Díaz, A., and J. M. Ortiz. 1995. Indirect voltammetric determination of carbaryl and carbofuran using partial least squares calibration. Anal. Chim. Acta 302:21—226. 9. Hartley, Ian C. and John P. Hart. 1994. Amperometric measurement of organophosphate pesticides using a screen-printed disposable sensor and biosensor based on cobalt phthalocyanine. Anal. Proc. incl. Anal. Comm. 31:333-337. 10. Kamrin, M. A. Ed.. 1997. Pesticide Profiles- Toxicity, Environmental Impact, and Fate. New York. Lewis Publisher. 11. Koile, Ross C. and Dennis C. Johnson. 1979. Electrochemical removal of phenolic films from a platinum anode. Anal.Chem. 51:741-744. 12. Liu, Guodong and Yuehe Lin. 2005. Electrochemical Sensor for Organophosphate Pesticides and Nerve Agents Using Zirconia Nanoparticles as Selective Sorbents. Anal. Chem. 77: 5894-5901. 13. Myers, Raymond H. 2000. Classical and Modern Regression with Applications. 2th ed. Pacific Grove, CA: Duxbury. 14. Næs, Tormod, Tomas Isaksson, Tom Fearn and Tony Davies. 2002. A User-Friendly Guide to Multivariate Calibration and Classification. UK: NIR Publications. 15. Ni,Yongnian, Ping Qiu and Serge Kokot. 2004. Simultaneous determination of three organophosphorus pesticides by differential pulse stripping voltammetry and chemometrics. Anal. Chim. Acta. 516:7-17. 16. Taylor, R. J. and A. A. Humffray. 1973. Electrochemical studies on glassy carbon electrodes I. electron transfer kinetics. Electroanalytical Chemistry and Interfacial Electrodechemistry. 42:347-354. 17. Wang, Joseph. 2000. Analytical Electrochemistry. 2th ed.. electronic book. John Wiley & Sons. 18. Wang, Joseph and Meng Shan Lin. 1988. In situ electrochemical renewal of glassy carbon electrodes. Anal.Chem. 60:499-502.zh_TW
dc.description.abstract目前在農藥檢測上所使用的方法費時,不適合進行現地量測之應用。 在本研究中採用循環伏安法進行加保利與加保伏兩種農藥殘留量之檢測,並且採用經典校正與逆校正法來建模。並且對兩種方法之擬合與預測進行比較。對於兩種農藥混合的檢測,使用偏最小平方法進行分析。即使伏安圖中兩種農藥的圖形重疊非常嚴重,此方法仍可以量測出混合液中各成分的含量。對於模式的檢定則是以標準誤、R2以及PRESS三個統計量為標準。zh_TW
dc.description.abstractIn routine procedures of measuring pesticides concentration were time-consuming. They can not be adopted for measuring concentration in situ. In this study, cyclic voltammetry (CV) was applied to measure the concentration of carbaryl and carbofuran. The classical calibration method and inverse calibration method were used for modeling. And the fitting and predicting ability of these two methods were compared. The analyses of the mixture of two pesticides were applied by partial least square method. This method can determine the compound individually from the mixture, even if the voltammograms of the two pesticides overlap strongly. The statistics for choosing the better models are standard error, R2 and PRESS.en_US
dc.description.tableofcontents摘要 i Abstract ii 目錄 iii 表目錄 vi 圖目錄 vii 第一章 緒論 1 1-1 前言 1 1-2 研究目的 1 第二章 文獻探討 2 2-1 農藥的分類 2 2-2 電化學方法應用於農藥偵測 3 2-3 電極的再生 5 2-5 循環伏安法 7 第三章 材料與方法 10 3-1 實驗設備 10 3-2 分析軟體 11 3-3 實驗材料 11 3-4 藥品與樣品處理 12 3-5 實驗步驟 13 3-7 應用到的統計分析技術 17 3-7-1 誤差變異估計值(estimate of error variance) 17 3-7-2 前進選取法(Forward Selection) 18 3-7-3 PRESS(Prediction Sum of Squares) 18 3-7-4 R-student統計量 19 3-7-5 經典校正(Classical Calibration)與逆校正(Inverse Calibration) 20 3-8 應用到的多變量分析技術 21 3-8-1主成分迴歸(Principal component regression, PCR) 21 3-8-2 偏最小平方迴歸(Partial least squares regression, PLS) 22 第四章 結果與討論 24 4-1 經典迴歸方法之建模 24 4-1-1 加保利濃度與面積A之關係 24 4-1-2 加保伏濃度與面積A之關係 31 4-1-3 加保利加入菜汁後濃度與面積B之關係 39 4-1-4 加保伏加入菜汁後濃度與面積B之關係 45 4-2 逆迴歸方法之建模 52 4-2-1 加保利濃度與面積A之關係 52 4-2-2 加保伏濃度與面積A之關係 55 4-2-3 加保利加入菜汁後濃度與面積B之關係 59 4-2-4 加保伏加入菜汁後濃度與面積B之關係 63 4-3 加保利與加保伏混合後濃度與面積A之關係 67 第五章 結論與建議 70 5-1 結論 70 5-2 建議 70 第六章 參考文獻 72zh_TW
dc.subjectin situ measurementen_US
dc.subjectcyclic voltammetry (CV)en_US
dc.subjectclassical calibrationen_US
dc.subjectinverse calibrationen_US
dc.titleDetermination of two kinds of pesticides by cyclic voltammetry and multivariate calibration methods.en_US
dc.typeThesis and Dissertationzh_TW
Appears in Collections:生物產業機電工程學系


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