Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3678
標題: 金屬鈦塊材的表面改質與其吸附應用
Surface Modification of Titanium bulk Materials and Its Adsorption Application
作者: 杜元瑋
Tu, Yuan-Wei
關鍵字: modification
改質
出版社: 化學工程學系所
引用: [1] J. Sagiv, Organized monolayers by adsorption. 1. formation and structure of oleophobic mixed monolayers on solid surfaces, Journal of the American Chemical Society 102 (1980) 92. [2] R. G. Nuzzo, F. A. Fusco, and D. L. Allara, Spontaneously organized molecular assemblies, 3. Preparation and properties of solution adsorbed monolayers of organic disulfides on gold surfaces, Journal of the American Chemical Society 109 (1987) 2358. [3] E. B. Troughton, C. D. Bain, G. M. Whitesides, R. G. Nuzzo, D. L. Allara, and M. D. Poter, Monolayer films prepared by the spontaneous self-assembly of symmetrical dialkyl sulfides from solution onto gold substrates: Structure, properties, and reactivity of constituent functional group, Langmuir 4 (1988) 365. [4] R. G. Nuzzo, L. H. Dobois, and D. L. Allara, Fundamental studies of microscopic wetting on organic surfaces. 1. Formation and structural characterization of a self-consistent series of polyfunctional organic monolayers, Journal of the American Chemical Society 112 (1990) 558. [5] R. Yamada, K. Uosaki, Structural investigation of the self-assembled monolayer of decanethiol on the reconstructed and (1×1) - Au (100) surfaces by scanning tunneling microscopy, Langmuir 17 (2001) 4148. [6] L. Li, S. Chen, S. Jiang, Protein adsorption on alkanethiolate self-assembled monolayers: Nanoscale surface structural and chemical effects, Langmuir 19 (2003) 2974. [7] F. Schreiber, Structure and growth of self-assembling monolayers, Progress in Surface Science 65 (2000) 151. [8] Y.-T. Tao, G. D. Hietpas, and D. L. Allara, HCl vapor-induced structural rearrangements of n-alkanate self-assembled monolayers on ambient silver, copper, and aluminum surfaces, Journal of the American Chemical Society 118 (1996) 6724. [9] M. E. Karaman, D. A. Antelmi, R. M. Pashley, The production of stable hydrophobic surfaces by the adsorption of hydrocarbon and fluorocarbon carboxylic acids onto alumina substrates, Colloids and Surface A 182 (2001) 285. [10] C.-S. Chang, S.-Y. Suen, Modiifcation of porous alumina membranes with n-alkanoic acids and their application in protein adsorption, Journal of Membrane Science 275 (2006) 70. [11] S. H. Y. Wang, K. McGinty, W. J. Brittain, Surface modification of a silicate substrate by a “grafting form”methodology utilizing a perester initiator, European Polymer Journal 42 (2006) 2053. [12] E. S. Gawalt, M. J. Avaltroni, N. Koch, J. Schwartz, Self-assembly and bonding of alkanephosphonic acids on the native oxide surface of titanium, Langmuir 17 (2001) 5736. [13] A. Kanta, R. Sedev, J. Ralston., The formation and stability of self-assembled monolayers of octadecylphosphonic acid on titania, Colloids and Surfaces A 291 (2006) 51. [14] M. G., E. Jaehne, T. Blaettler, T. Blaettler, M. Textor, H.-J. P. Adler, Carboxy-terminated oligo(ethylene glycol) - alkane phosphate: synthesis and self-assembly on titanium oxide surfaces, Langmuir 23 (2007) 377. [15] Q. Liu, J. Ding, F. K. Mante, S. L. Wunder, G. R. Baran, The role of surface functional groups in calcium phosphate nucleation on titanium foil: a self-assembled monolayer technique, Biomaterials 23 (2002) 3013. [16] A. Nanci, J. D. Wuest, L. Peru, P. Burnet, V. Sharma, S. Zalzal, M. D. McKeel, Chemical modification of titanium surfaces for covalent attachment of biological molecules, Journal of Biomedical Materials Research 40 (1998) 324. [17] E. Mahe´, D. Devilliers, Surface modification of titanium substrates for the preparation of noble metal coated anodes, Electrochimica Acta 46 (2000) 629-636 [18] H.-H. Huang, S.-J. Pan, Y.-L. Lai, T.-H. Lee, C.-C. Chen, F.-H. Lu, Osteoblast-like cell initial adhesion onto a network-structured titanium oxide layer, Scripta Materialia 51 (2004) 1017. [19] J. A. Lori, T. Hanawa, Adsorption characteristics of albumin on gold and titanium metals in Hanks solution using EQCN, Spectroscopy 18 (2004) 545 [20] E. Jansson,, P. Tengvall, Adsorption of albumin and IgG to porous and smooth titanium, Colloids and Surfaces B 35 (2004) 45. [21] E. Stathatos, D. Tsioourvas, P. Lianos, Titanium dioxide films made from reverse micelles and their use for the photocatalytic degradation of adsorbed dyes, Colloids and Surface A 149 (1999) 49. [22] B. Zielinska, J. Grzechulska, J. Kalenczuk, A. W. Morawski, The ph influence on photocatalytic decomposition of organic dyes over A11 and P25 titanium dioxide, Applied Catalysis B 45 (2003) 293. [23] C.-C Chen, C.-S Lu, F.-D Mai, C.-S Weng, Photooxidative N-de-ethylation of anionic triarymethane dye (sulfan blue) in titanium dioxide dispersions under UV irradiation, Journal of Hazardous Materials B 137 (2006) 1600. [24] K. Asami, Y. Takada, O. Okuno, Adsorption of released ions from dental amalgams on titanium, Surface and Interface Analysis 34 (2002) 144. [25] J. R. Mann, D. F. Watson, Adsorption of CdSe nanoparticles to thiolated TiO2 surface: influence of intralayer disulfide formation on CdSe surface coverage, Langmuir 23 (2007) 10924. [26] F.-H. Lu, Y.-S. Yang, Titanium dioxide film synthesizing method, R.O.C. (Taiwan) No. 1246986. [27] C.-Yi Wu, S.-Yi Suen, S.-C. Chen, J.-H. Tzeng, Analysis of protein adsorption on regenerated cellulose-based immobilized copper ion affinity membranes, Journal of Chromatography A 996 (2003) 53. [28] H..-L Hu, M.-Y Wang, C.-H Chung, S.-Y Suen, Purification of VP3 protein of infectious bursal disease virus using nickel ion-immobilized regenerated cellulose-base membranes, Journal of chromotrophy B 840 (2007) 76. [29] G. J. Hwang, H. Ohya, T. Nagai, Ion exchange membrane based on block copolymers. Part III :Preparation of cation exchange membrane, Journal of Membrane Science 156 (1999) 61. [30] N. Agoudjil, T. Benkacem, Synthesis of porous titanium dioxide membranes, Desalination 206 (2007) 531. [31] W.-J Liang, C.-P. Wu, P.-L. Kuo, Solid Polymer Electrolytes X: Preparation and Characterizations of Polyether-Siloxane, Organic-Inorganic, Hybrid NanocompositeComplexed with Lithium Perchlorate, Journal of Polymer Science: Part B: Polymer Physics 42 (2004) 1928. [32] Y.-C. Chu, C.-C. Wang, C.-Y. Chen, A new approach to hybrid CdS nanoparticles in poly(BA-co-GMA-co-GMA-IDA) copolymer membranes, Journal of Membrane Science 247 (2005) 201.
摘要: In this study, titanium (Ti) bulk materials of different surface treatments were oxidized with H2O2 which appeared porous structure and crystal structure of Ti bulk materials surfaces by field-emission scanning electron microscope (FE-SEM) and wide-angle X-ray diffraction (WXRD) and then modified with n-octadecanoic acid (C17COOH) using SMAs method. The Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) spectra revealed hydrophilic functional group after H2O2 oxidation and hydrophobic functional group of n-octadecanoic acid represented that Ti bilk materials surfaces successfully modified with n-octadecanoic acid. The properties and variation of after oxidation and after n-octadecanoic acid modification of Ti bilk materials surfaces were characterized by atomic force microscope (AFM), contact angle, energy dispersive spectrometer (EDS), and ATR-FTIR showed that the optimum surface treatment of Ti bulk material was grind. After oxidation and n-octadecanoic acid modification, the hydrophilic and hydrophobic properties were exhibited higher adsorption percentage except for TiO2 layer using potentiodynamic anodization treatment. Doxepin adsorption results exhibit that hydrophilic surfaces of Ti bulk materials after oxidation were higher than that of hydrophobic surfaces of Ti bulk materials and also proved that the optimum surface treatment of Ti bulk material was grind. Epichlorohydrin (EPI) and Iminodiacetic aicd (IDA) reacted with ground Ti bulk materials surfaces which after oxidation by ATR-FTIR and EDS measurements established the surface reaction. Finally, adsorption of Methyl violet, Cibacron blue 3GA and Cibacron red 3BA of ground Ti bulk materials surfaces were observed and the max copper ion capacity of ground Ti materials surfaces was 0.139 (μmol/cm2).
URI: http://hdl.handle.net/11455/3678
其他識別: U0005-1211200816085500
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-1211200816085500
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