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標題: 金屬鈦塊材的表面改質與其吸附應用
Surface Modification of Titanium bulk Materials and Its Adsorption Application
作者: 杜元瑋
Tu, Yuan-Wei
關鍵字: modification
出版社: 化學工程學系所
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摘要: In this study, titanium (Ti) bulk materials of different surface treatments were oxidized with H2O2 which appeared porous structure and crystal structure of Ti bulk materials surfaces by field-emission scanning electron microscope (FE-SEM) and wide-angle X-ray diffraction (WXRD) and then modified with n-octadecanoic acid (C17COOH) using SMAs method. The Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) spectra revealed hydrophilic functional group after H2O2 oxidation and hydrophobic functional group of n-octadecanoic acid represented that Ti bilk materials surfaces successfully modified with n-octadecanoic acid. The properties and variation of after oxidation and after n-octadecanoic acid modification of Ti bilk materials surfaces were characterized by atomic force microscope (AFM), contact angle, energy dispersive spectrometer (EDS), and ATR-FTIR showed that the optimum surface treatment of Ti bulk material was grind. After oxidation and n-octadecanoic acid modification, the hydrophilic and hydrophobic properties were exhibited higher adsorption percentage except for TiO2 layer using potentiodynamic anodization treatment. Doxepin adsorption results exhibit that hydrophilic surfaces of Ti bulk materials after oxidation were higher than that of hydrophobic surfaces of Ti bulk materials and also proved that the optimum surface treatment of Ti bulk material was grind. Epichlorohydrin (EPI) and Iminodiacetic aicd (IDA) reacted with ground Ti bulk materials surfaces which after oxidation by ATR-FTIR and EDS measurements established the surface reaction. Finally, adsorption of Methyl violet, Cibacron blue 3GA and Cibacron red 3BA of ground Ti bulk materials surfaces were observed and the max copper ion capacity of ground Ti materials surfaces was 0.139 (μmol/cm2).
其他識別: U0005-1211200816085500
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