Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3832
標題: 側鏈含三苯胺之P型共軛高分子合成及其在太陽能電池應用與光電性質探討
Synthesis and Photovoltaic Properties of a Series of Triphenylamine Pendant Containing P-type Conjugated Polymers.
作者: 陳遠鵬
Chen, Yuan-Peng
關鍵字: Triphenylamine
三苯胺
polymer solar cells
HOMO
Voc
太陽能電池
能階
開路電壓
出版社: 化學工程學系所
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摘要: 本研究針對共軛高分子HOMO能階進行調控,克服高分子太陽能電池在氧化穩定性與開路電壓的問題。透過Stille與Suzuki coupling共聚反應合成一系列P型共軛高分子,皆可溶於一般有機溶劑並具備良好熱穩定性。由光譜與電化學性質得知,共軛高分子側鏈導入三苯胺可使材料吸收光譜增寬,並有效調整HOMO能階。將材料製成元件後進行光伏特性質量測,高分子主鏈因含未取代共軛單元,使太陽能電池獲得較佳的開路電壓。觀察材料與PC61BM混摻型態顯示,主鏈因含未取代共軛單元,能提供有效空間使共軛高分子與PC61BM混摻相容性提升。其中主鏈含二苯乙烯且側鏈含三苯胺之共軛高分子與PC61BM 1:1 (w/w) 混摻之太陽能電池開路電壓為0.83 V,光電轉換效率為0.48 %。
P-type conjugated polymers containing pendant triphenylamines were synthesized via Stille and Suzuki coupling reactions. All polymers exhibited good solubility in common organic solvents and stable thermal properties. The introduction of triphenylamines as side chains would broaden the absorption of solar spectra and modulate the HOMO levels of polymers. With the presence of unsubstituted conjugated moieties in main chain, the HOMO level was lowered. Consequently, a larger open circuit voltage of polymer-based solar cell was obtained. Sufficient free volume was provided by unsubstituted conjugated moieties in the polymer main chain, which improved the miscibility of bulk heterojunction observed by an optical microscope. Our preliminary results exhibited a power conversion efficiency of 0.48 % and a Voc of 0.83 V under illumination AM 1.5, 100 mW/cm2. This suggests that the conjugated polymer comprising pendant triphenylamines are potentially useful for solar cell applications.
URI: http://hdl.handle.net/11455/3832
其他識別: U0005-2008201011251400
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-2008201011251400
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