Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/41630
標題: Green Conversion of Phenolic Compound to Benzoate Over Polymer-Supported Phase-Transfer Catalysts
作者: Yang, H.M.
楊鴻銘
Huang, C.C.
關鍵字: Esterification
Polymer-supported phase-transfer catalyst
Trialkylamines
Phenyl benzoate
Triphase catalysis
triphase catalysis
reactor
期刊/報告no:: Catalysis Letters, Volume 128, Issue 1-2, Page(s) 235-242.
摘要: The conversion of sodium phenoxide into benzoates over polymer-supported phase-transfer catalysts with trialkylamines as the functional groups (triphase catalysis) was investigated. The yield of product phenyl benzoate was 100% in 1 h of reaction using a small amount of tributylamine catalyst supported on 1.38% divinylbenzene (DVB) cross-linked copolymer (40-80 mesh) of styrene and chloromethylstyrene. During the reaction, the catalyst stays between the aqueous and organic phases. The overall reaction rate was strongly dependent on the stirring speed and the ionic exchange of Cl(-) of the catalyst with PhO(-) in the interfacial region. The reaction rate decreased with increasing the mean particle sizes for 1.38% DVB catalyst. The variation of the catalytic intermediate within the catalyst was determined to verify the reaction mechanism. A kinetic model was also proposed to correlate the reaction rate constants. The efficient conversion of phenolic compounds over polymer-supported catalysts shows that triphase catalysis is an efficient green technology in chemical synthesis.
URI: http://hdl.handle.net/11455/41630
ISSN: 1011-372X
文章連結: http://dx.doi.org/10.1007/s10562-008-9744-6
Appears in Collections:化學工程學系所

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