Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/5231
標題: 常溫下過硫酸鹽氧化三氯乙烯之研究
Investigation on persulfate oxidation of trichloroethylene (TCE) at ambient temperatures.
作者: 王子欣
Wang, Zih-Sin
關鍵字: in-situ chemical oxidation (ISCO)
現址化學氧化法
sulfate radical
thermally activated
radical scavengers
硫酸根自由基
熱活化
自由基攫取者
出版社: 環境工程學系所
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摘要: 本研究探討土壤及地下水現址化學氧化整治方式(ISCO)之氧化劑過硫酸鹽(persulfate, S2O82-)於常溫下的應用,S2O82-(E° = 2.01 V)經熱或化學方式活化可產生硫酸根自由基強氧化劑(SO4-‧, E° ~ 2.6 V),SO4-‧可氧化許多有機污染物質,例如三氯乙烯(trichloroethylene, TCE),然而若經激發活化之氧化程序雖可達到快速之反應,但通常亦同時造成快速之S2O82-降解及較高氧化劑使用量,因此實驗設計以探討於10、20及30 °C下,S2O82-氧化分解水溶液中TCE之效能,並進一步探究S2O82-應用於ISCO時之限制因子如溶液中pH值、離子強度及自由基攫取者如氯離子(Cl-)、碳酸氫/碳酸根(HCO3-/CO32-)等離子對反應之影響。 pH影響之結果顯示,在實驗設計pH範圍中(pH = 4, 7, 9),於系統溫度10、20及30 °C時,TCE之最大降解速率發生於pH 7,增加或降低溶液中pH值皆使反應速率降低,且於低pH條件下反應速率之降低程度較提高pH時顯著。在不同pH條件下鑑別主要作用自由基實驗中發現,酸性條件下,水溶液中主要作用之自由基為SO4-‧,鹼性條件下則為氫氧根自由基(‧OH)。 此外,於20 °C下,自由基攫取者之實驗結果顯示,在pH 7環境下,溶液中HCO3-/CO32-之濃度範圍於0 ~ 9.20 mM之間,碳酸根離子並不會對TCE降解速率造成影響。當溶液中Cl-濃度小於0.20 M時並不會對氧化反應速率造成影響。以地下水及純水為實驗水體之比較實驗中證實,於地下水中TCE之降解速率高於以純水為實驗水體時之降解速率,推論此一現象乃因反應過程pH值之變化所造成。 因此過硫酸鹽於ISCO之應用上,應先行評估場址地下水之化學組成,如地下水之pH緩衝能力,及可能之影響因子如Cl-及HCO3-/CO32-等濃度範圍,以評估ISCO應用之可行性。
In-situ chemical oxidation (ISCO) is a technology used for groundwater remediation. Persulfate (S2O82-, E° = 2.01 V) is an oxidant for application of ISCO. S2O82- can be thermally or chemically activated to produce a powerful oxidant sulfate free radical (SO4-‧, E° ~ 2.6 V) which can potentially destroy many organic contaminants such as trichloroethylene (TCE). However, althought activation process can increase oxidation rate but it also caused more oxidant consumption. This laboratory study investigated the efficiency on the persulfate oxidation of TCE at near ambient temperature (10, 20 and 30 °C) and the influence of pH and radical scavengers such as chloride ion (Cl-) and alkanility species (i.e., HCO3-/CO32-) on the oxidation.. Under the range of temperatures tested, the maximum rate of TCE degradation occurred at near neutral pH (i.e., pH 7). Increases and decreases in pH resulted in decreases in TCE degradation rates. Radical scavenging tests used to identify predominant radical species suggested that SO4-‧ predominates under acidic conditions and the hydroxyl radical (‧OH) predominates under basic conditions. It was found that TCE degradation by persulfate was not affected by the presence of HCO3-/CO32- for concentrations within the range of 0 ~ 9.2 mM at 20°C and pH 7. The presence of Cl- concentration below 0.2 M revealed no effect on TCE degradation rate. However, at Cl- levels greater then 0.2 M, TCE degradation rate was seen to reduce with increases in Cl- concentration. In a side by side comparison of groundwater vs. unbuffered RO water tests, it was seen that when the pH is buffered due to the presence of groundwater constituents the observed TCE degradation rate is higher than that in RO water where pH dropped from neutral to acidic.
URI: http://hdl.handle.net/11455/5231
其他識別: U0005-2906200616570100
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