Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/5520
標題: 以可見光光觸媒對揮發性有機物之光催化研究
A study on visible photocatalysts for decomposition of VOC
作者: 黃柄橓
Huang, Bing-Shun
關鍵字: Visible photocatalyst
可見光光觸媒
sol-gel method
VOCs
溶膠凝膠法
揮發性有機物(VOCs)
出版社: 環境工程學系所
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摘要: 本研究探討不同種型態可見光光觸媒之優劣,進行複合半導體和非金屬原子摻雜之比較,使用甲醇揮發性有機物做為活性測試之標的物,並以商業觸媒為比較基準。藉由FE-SEM、XRD、TEM、XPS、UV-VIS 和BET等分析,以觀察觸媒表面型態(morphology)與觸媒特性,並與實驗結果相互佐證。 實驗首先探討影響溶膠凝膠法之製備參數,結果顯示在製備條件為pH2 時,其粒徑大小和分散性最佳,平均粒徑約在8 nm 左右。後續之可見光光觸媒改質,分別摻雜多壁奈米碳管和氮原子,並找出最佳之製備參數。首先複合半導體光觸媒之改質,為改變不同MWCNT 和TiO2 之比例,在MWCNT/TiO2 重量比為20 %,有最佳之光催化效率; 氧缺陷型光觸媒(TiO2-x),為使用氮原子摻雜(TiO2-xNx)以增進光觸媒於可見光之活性,並探討氮原子摻雜的比例(N/Ti)對光催化活性之影響,結果顯示摻雜氮原子的多寡對光催化效率影響不大。 將複合半導體(MWCNT-TiO2)和非金屬原子摻雜(TiO2-xNx)進行比較,其XRD 結果顯示摻雜多壁奈米碳管和氮原子對晶相皆不會有明顯改變;由FE-SEM 和TEM 結果顯示,改質前後的粒徑大小皆約為8nm。其光催化活性結果顯示非金屬原子摻雜(TiO2-xNx)> 複合半導體(MWCNT-TiO2)>Degussa P25; 故在本實驗之可見光光觸媒改質,非金屬原子摻雜優於複合半導體改質。
URI: http://hdl.handle.net/11455/5520
其他識別: U0005-2606200817101000
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-2606200817101000
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