請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/5804
標題: 以UV/TiO2光催化處理實場染整廢水之可行性研究
Feasibility study on the treatment of real dyeing wastewater by UV/TiO2 photocatalytic process
作者: 蔡明穎
Tsai, Ming-Ying
關鍵字: 二氧化鈦
TiO2,
染整廢水
光催化
Dyeing wastewater
Photocatalytic
出版社: 環境工程學系所
引用: 1.中文部分 圖書 尹邦躍,2003,「奈米時代」,五南圖書出版股份有限公司。 王敏泰,1982,「染料化學」,五洲出版社。 汪輝雄著,纖維染色學,大學圖書供應社,p.197~198,1988。 胡振國譯,1989,「半導體元件-物理與技術」,全華圖書公司。 經濟部工業局,1993,染整工業「工業減廢技術手冊」。 經濟部工業局,1994,染整工業「染整業水污染防治技術手冊」。 經濟部中小企業處,「中小企業白皮書」,2006。 謝芳生、劉濱達譯,Jacob Millman and Arvin Grabel 著,1986,「微電子學,東華書局」。 期刊與論文 江佳玲、張鎮南、黃柯倫,2007,「探討臭氧結合紫外光反應去除腐殖酸之降解情形」,東海科學學報,第九卷,pp. 15-28.。 林憶芳,1995,「利用UV/H2O2 光化學氧化法處理含酸性染料廢水 研究」,國立中興大學環境工程學研究所,碩士論文。 洪雲傑,2005,「以活性碳擔持二氧化鈦觸媒及其性質鑑定」, 國立中興大學環境工程學系,碩士論文。 胡正苓,2007,「以可見光催化V-TiO2 光觸媒降解亞甲基藍之研究」,國立中興大學環境工程學系,碩士論文。 連建智,2010,「利用光催化反應處理染整廢水之可行性研究」, 國立中興大學環境工程學系,碩士論文。 陳姍玗、簡良榮、張嘉修、陳博彥,2000,「以混合菌相進行廢水褪色之生態工程研究」,第二十五屆廢水處理技術研討會論文集,pp.6-11。 游勝傑、歐尚鑫、曾迪華,2004,「薄膜生物反應槽處理韓染整工業廢水之研究」,第九屆水再生及再利用研討會論文集,pp.245-256。 葉志揚,2000,「以溶液凝膠法製備二氧化鈦觸媒及其性質鑑定」, 國立台灣大學化學工程研究所,碩士論文。 廖盛焜,1982,「反應性染料之發展動向」,紡織科學期刊44期。 劉全得,2005,「偶氮染料之二氧化鈦光催化脫色反應特性研究」, 國立高雄第一科技大學環境與安全衛生工程系,碩士論文。 魏漣邦、張敏超、楊耿豪、許楹昇,2000,「化學混凝脫色最佳組合劑量之研究」,第二十五屆廢水處理技術研討會論文集,pp.674-678。 2.西文部分 Akkaya, G., Uzun, I. and Guzel, F., (2007), " Kinetics of the adsorption of reactive dyes by chitin " Dyes and Pigments, Vol.73, pp.168-177. Barakat, M. A., (2011). "Adsorption and photodegradation of Procion yellow H-EXL dye in textile wastewater over TiO2 suspension" Journal of Hydro-environment Research, Vol.5, pp.137-142. Bras, R., Gomes, A., Ferra, M. I. A., Pinheiro, H. M. and Goncalves, I. C., (2005)," Monoazo and diazo dye decolourisation studies in a methanogeic UASB reactor ", Journal of Biotechnology, Vol.115, pp.57-66. Oliveira, D. F. M., Batista, P. S., Muller Jr. P. S. , Velani ,V.,Franca ,M. D., Souza , D. R., and Machado, A. E. H., (2011).” Evaluating the effectiveness of photocatalysts based on titanium dioxide in the degradation of the dye Ponceau 4R.” Dyes and Pigments,Vol.92, pp.563-572. Doede, C. M. and Walker, C. A., (1955). “Photochemical Engineering,” Chemical Engineering journal, Vol. 62, 159-178. Eren, Z. and Acar, F. N., (2006), " Adsorption of reactive black 5 from an aqueous solution:equilibrium and kinetic studies "Desalination. Vol.194, pp.1-10. Finklea, H.O.(1988).”Semiconductor electrode.”Elsevier Press, New York. Gratzel, M., (1983). “Energy Resources through Photochemistry and Catalysis.” Acadamic Press Inc. Gupta ,V.K., Jain, R., and Mittal, A.,(2012). " Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions "Materials Science and Engineering: C. Vol. 32,, pp. 12–17. Hathaisamit, K., Sutha, W., Kamruang , P., Pudwat, S., Teekasap, S.,(2012). " Decolorization of Cationic Yellow X-Gl 200% from Textile Dyes by TiO2 Films-Coated Roto" Procedia Engineering Vol.32, pp.800-806. Ivanov, Y. G., Rudakova, E. V., Chamaev, V. N. and Matuskov, Y. E., (1989), " Effect of tjionsulfate and of sulfide on biochemical of oxidation of surface-active substances " Fibre Chemistry, Vol.20, pp.306-309. Kim, E. J. and Hahn, S. H., (2001),"Microstructure and photoactivity of titania nanoparticles prepared in nonionic W/O microemulsions." Material Science and Engineering A, Vol. 303(1-2), pp.24-29. Kim, E. J., Oh, S. H. and Hahn, S. H., (2001), "Influence of calcination on microstructures and photoactivities of alkoxide-derived TiO2 nanoparticles prepared in W/O microemulsions." Chemical Engineering Communications, Vol. 187,pp.171-184. Liang, C. H., Li, F. B., Liu, C. S., Lu, J. L. and Wang, X. G., (2008), " The enhancement of adsorption and photocatalytic activity of rare earth ions doped TiO2 for the degradation of Orange I ", Dyes and Pigments, Vol.76, pp.477-484. Natarajan, T.S., Thomas, M., Natarajan,K., Bajaj, H. C., and Tayade, R. J.,(2011). " Study on UV-LED/TiO2 process for degradation of Rhodamine B dye" Chemical Engineering journal, Vol. 169, pp.126-134. Nguyen-Phan, and T. D.,Shin, E. W.,(2011), " Morphological effect of TiO2 catalysts on photocatalytic degradation of methylene blue"Journal of Industrial and Engineering Chemistry, Vol.17, pp.397-400. Pizzolato, T. M., Carissimi, E., Machado, E. L. and Schneider, I.A.H., (2002), " Colour removal with NaClO of dye wastewater from an agate-processing plant in Rio Grand do Sul, Brazil" International Journal of Mineral Processing, Vol.65, pp.203-211. Prengle, H. W. and Mauk, C. E., (1977), "New technology: Ozone/UV chemical oxidation waste water process for metal complexes, organic species and disinfection" AIChE Symposium Series, Vol. 74, pp.228-244. Janisch, R., Gopal, P., and Spaldin, N. A.,(2005), " Transition metaldoped TiO2 and ZnO-present status of the field" Journal of Physics Condensed Matter, Vol. 17,(27), pp.657–689. Sadik, W. A.,(2007), "Decolourization of an azo dye by heterogeneous photocatalysis",Institute of Graduate Studies and Research—Materials Science, Alexandria, Egypt. Saleh, N., Kim, H. J., Phenrat, T., Matyjaszewski, K., Tilton, R. D. and Lowry, G. V., (2008), " Inoic, strength and composition affect the mobility of surface-modified Fe0 nanoparticle in water-saturated sand columns " Environmental Science & Technolog, Vol.42, pp.3349-3355. Sin, J.C., Lam, S.M., Mohamed, A.R., and Lee,K.T., (2011), " Degrading endocrine disrupting chemicals from wastewater by TiO2 photocatalysis: a review" International Journal of Photoenergy, Vol. 2012. Stumm, W., (1992), "Chemstry of the solid-water interface" John Wiley & Sons, New York. Tunay, O., (1990), " Pretreatment of textili processing wastewater " Water Science and Technology, Vol.22, pp.17-20. Turro, N. J. (1965). "Molecular Photochemistry Columbia University, N. Y. Wei, Z., Linda, Z., and Lianzhou, W., (2009). "Photocatalytic TiO2/adsorbent nanocomposites prepared via wat chemical impregnation for wastewater treatment: A revivew" Applied Catalysis A: General, Vol.371, pp.1-9. Xu, J., Ao, Y., Fu, D. and Yuan, C., (2009), " Study on photocatalytic performance and degraddation kinetics of X-3B with lanthanide-modified titanium dioxide under solar and UV illumination "Journal of Hazardous Materials, Vol.164, pp.762–768. Zepp, R. G., (1988). “Factors affecting the photochemical treatment of hazardous waste,” Environmental Science and Technol, Vol. 22, pp.256-257.
摘要: 本研究以溶膠凝膠法(Sol-gel Method)製備二氧化鈦(TiO2)光觸媒,並以實場之染整廢水當作目標污染物,廢水來源分別為實場原廢水與實場經生物處理後之廢水。 實驗方法採批次懸浮式反應槽進行光催化實驗。實驗控制不同廢水來源、不同 pH 值 (4、7、10)、光觸媒添加劑量 (0.1 g/L、0.2 g/L)等操作參數,對於光催化反應之色度去除率、化學需氧量和礦化率之影響,進而探討利用光催化處理實廠染整廢水之可行性。 實場原廢水部分,在 pH 7光觸媒添加量 0.2 g/L 下有最佳之礦化率 (32.0 %)及 COD 去除率 (50.8 %),而在觸媒添加量 0.2 g/L 下色度去除率於 pH 4、pH 7、pH 10分別為 62.7 % 、56.0 % 及 49.0 %。經生物處理後廢水部分在 pH 7 光觸媒添加量 0.1 g/L下有最佳之礦化率 (45.5%) 及 COD 去除率 (53.0 %),而在 pH 7 光觸媒添加量 0.2 g/L 下有最佳之色度去除率 (63.0 %)。 綜合本研究實驗結果,欲利用二氧化鈦光催化降解染整廢水,廢水先經過生物處理之後再使用光催化處理可以有效提升礦化率,應將光催化處理系統接於生物處理系統後端,較能有效發揮光催化之能力。
In this study, preparation of titanium dioxide (TiO2) was synthesized by sol-gel method. The target pollutant was real dyeing wastewater sampled from after primary treatment and bio-treatment respectively. The photocatalysis experimental method used suspended batch reactor. The manipulation parameters included the pH value (4, 7, 10) and dosages of photocatalyst (0.1 g/L, 0.2 g/L) affected the color residual, chemical oxygen demand (COD) and mineralization efficiency. Therefore, explore the feasibility of photocatalytic applied to real dyeing wastewater. The results of the real dyeing wastewater showed that the best mineralization efficiency (32.0 %) and COD removal rate (50.8 %) on the condition of 0.2 g/L photocatalyst in pH 7, and the color residual rate of 0.2 g/L photocatalyst in pH 4, 7, 10 was individually 62.7 %, 56.0 % and 49.0 %. On the other hand, the results of the bio-treatment wastewater revealed the best mineralization efficiency (45.5%) and COD removal rate (53.0%) on the condition of adding 0.1 g/L dosage of photocatalyst in pH 7. In addition, the best color residual rate (63.0%) work on 0.2 g/L photocatalyst in pH 7. The conclusion of this study, it could enhance the mineralization efficiency of the dyeing wastewater in photocatalysis by TiO2 after bio-treatment. So the photocatalytic system work more efficiency behind the bio-treatment.
URI: http://hdl.handle.net/11455/5804
其他識別: U0005-1007201215561400
文章連結: http://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-1007201215561400
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