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標題: Bis 1,3(eta(3))-allyl mu-2(eta(4))-1,3-bis(diphenylphosphino)-2,4-diphe nylcyclobuta-1,3-diene-1:3 kappa P-2:P ' dichlorido-1 kappa Cl,3 kappa Cl- 2(eta(5))-isopropylcyclopentadienyl -2-cobalt(I)-1,3-dipalladium(II) dichloromethane solvate
作者: Chang, C.P.
Hong, F.E.
期刊/報告no:: Acta Crystallographica Section E-Structure Reports Online, Volume 65, Page(s) M669-U682.
摘要: In the title complex, [CoPd2(C3H5)(2)(C8H11)Cl-2(C40H30P2)]center dot-CH2Cl2, the Co-I atom is sandwiched between the cyclopentadienyl and cyclobutadiene rings. The two diphenylphosphine substituents of the cyclobutadiene ring are situated opposite to each other and bind two Pd-II atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloromethane solvent molecule (equal occupancies) and one C atom and its attached H atom of each of the allyl ligands (occupancies 0.55:0.45) are disordered.
ISSN: 1600-5368
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