Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/68625
標題: A reversible octahedral to trigonal-bipyramidal cobalt coordination change in an aquo-accessible coordination network
作者: Fu, S.J.
Cheng, C.Y.
Lin, K.J.
關鍵字: single-crystal transformations
open-framework
porous material
complexes
polymers
4,4-bipyridine
rehydration
dehydration
catalysis
binding
期刊/報告no:: Crystal Growth & Design, Volume 7, Issue 8, Page(s) 1381-1384.
摘要: An aquo-accessible chromatic change in a crystal was induced by means of a reversible coordination geometry shift from octahedra in [Co(C12H8N2)(HO3P-C2H4-PO3H)(OH2)(2)] (1) to trigonal-bipyramid in [Co(C12H8N2)(HO3P-C2H4-PO3H)] (2) at the cobalt(II) center; the crystal-to-crystal phase transition was confirmed by powder X-ray diffraction and solid-state UV-vis diffuse reflectance spectra.
URI: http://hdl.handle.net/11455/68625
ISSN: 1528-7483
文章連結: http://dx.doi.org/10.1021/cg070361r
Appears in Collections:期刊論文

文件中的檔案:

取得全文請前往華藝線上圖書館



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.