Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/69826
DC FieldValueLanguage
dc.contributor.authorDatta, A.en_US
dc.contributor.authorChuang, N.T.en_US
dc.contributor.authorLiao, F.X.en_US
dc.contributor.authorHu, C.H.en_US
dc.contributor.authorHuang, W.Y.en_US
dc.contributor.authorHuang, J.H.en_US
dc.contributor.authorDas, K.en_US
dc.contributor.authorGamez, P.en_US
dc.contributor.authorCosta, J.S.en_US
dc.date2010zh_TW
dc.date.accessioned2014-06-11T05:58:58Z-
dc.date.available2014-06-11T05:58:58Z-
dc.identifier.issn1747-5198zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/69826-
dc.description.abstractA singly phenoxido-bridged dinuclear Cu-II complex, [Cu-2(L)(2)(SCN)(2)(H2O)], has been obtained from a Schiff-base ligand (2-[{[2-(dimethylamino)ethyl]imino}methyl]-6-methoxyphenol), generated by condensation of o-vanillin with N,N-dimethylethane-1,2-diamine. The Cu(II) complex has been fully characterised by analytical, spectroscopic, magnetic susceptibility and EPR measurements and DFT calculations, as well as single-crystal X-ray diffraction analysis. It consists of two geometrically distinct square-pyramidal and octahedral copper(II) centres, exhibiting N2O3 and N4O2 donor sets. In the dimeric unit, the copper atoms are connected by a mu(2)-phenolato oxygen atom, belonging to one bridging Schiff-base ligand. Variable-temperature magnetic susceptibility measurements indicate strong antiferromagnetic exchange interactions between the Cu(II) centres, with a 2J value of -89(1) cm(-1).en_US
dc.language.isoen_USzh_TW
dc.relationJournal of Chemical Researchen_US
dc.relation.ispartofseriesJournal of Chemical Research, Issue 11, Page(s) 637-640.en_US
dc.relation.urihttp://dx.doi.org/10.3184/030823410x12886325735063en_US
dc.subjectcopper(II)en_US
dc.subjectphenoxido-bridgeen_US
dc.subjectspectroscopic studyen_US
dc.subjectantiferromagneticen_US
dc.subjectcouplingen_US
dc.subjectcopper(ii) complexesen_US
dc.subjectcrystal-structureen_US
dc.subjectactive-siteen_US
dc.subjectdicopper(ii)en_US
dc.subjectcomplexen_US
dc.subjectbiological relevanceen_US
dc.subjectmacrocyclic liganden_US
dc.subjectgalactose-oxidaseen_US
dc.subjectrecognitionen_US
dc.subjectmononuclearen_US
dc.subjectreceptorsen_US
dc.titleA dissymmetric, singly phenoxido-bridged Cu-II dinuclear coordination compound: synthesis, characterisation, magnetic and computational studyen_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.3184/030823410x12886325735063zh_TW
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