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|標題:||A doubly end-on azido-bridged trinuclear Cu(II) complex: synthesis, spectral and DFT functional studies|
|期刊/報告no：:||Journal of Chemical Research, Issue 3, Page(s) 140-143.|
|摘要:||A trinuclear, doubly azido-bridged Cu(II) complex, [Cu(1.50)(L)(N(3))(3)(CH(3)OH)](2), (LH = [(CH(3))(2)NCH(2)CH(2)N=CHC(6)H(3)(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent Cu(II) ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.|
|Appears in Collections:||期刊論文|
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