Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/70354
標題: Extended metal-atom chains with an inert second row transition metal: Ru(5)(mu(5)-tpda)(4)X(2) (tpda(2-) = tripyridyldiamido dianion, X = Cl and NCS)
作者: Yin, C.X.
Huang, G.C.
Kuo, C.K.
Fu, M.D.
Lu, H.C.
Ke, J.H.
Shih, K.N.
Huang, Y.L.
Lee, G.H.
Yeh, C.Y.
Chen, C.H.
Peng, S.M.
關鍵字: string complexes
crystal-structure
magnetic-properties
gold atoms
conductance
electron
ligands
bonds
tetrapyridyltriamine
ni-6(12+)
期刊/報告no:: Journal of the American Chemical Society, Volume 130, Issue 31, Page(s) 10090-+.
摘要: EMACs (extended metal-atom chains) offer a unique platform for the exploration of metal-metal interactions. There has been significant advances on the synthesis of EMACs, such as lengthening the chains up to 11 metal atoms thus far, integrating naphthyridine molecules for tuning the charge carried at metal centers, and manipulation of metal-metal interactions. However, the metal centers in EMACs hitherto are limited to first row transition metals which are more labile than those relatively inert ones with electrons filled in the 4d and 5d shells. In this Communication, the synthesis, crystallographic, magnetic and electrical conduction.
URI: http://hdl.handle.net/11455/70354
ISSN: 0002-7863
文章連結: http://dx.doi.org/10.1021/ja8016818
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