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標題: Novel route to (+)-pinitol intermediate via a strategy derived from diazotization of O-isopropylidene-protected 4-amino-2-cyclohexen-1-ol
作者: Lin, K.W.
Wang, Y.C.
Yan, T.H.
關鍵字: diazotization
internal substitution
asymmetric cycloaddition
microbial oxidation
期刊/報告no:: Journal of the Chinese Chemical Society, Volume 55, Issue 2, Page(s) 418-420.
摘要: A concise preparation of the enantiopure 1,2-(isopropylidenedioxy)-3,4-epoxy-5-cyclohexene 2b, which is an important building block for (+)-pinitol synthesis, evolved by combining the asymmetric cycloaddition of isopropylidenedioxy)cyclohexadiene to chiral chloronitroso with an internal substitution of an amino alcohol to create vinyl epoxide.
ISSN: 0009-4536
Appears in Collections:期刊論文



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