Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/71415
標題: Using Diels-Alder reactions to synthesize 2 rotaxanes under solvent-free conditions
作者: Hsu, C.C.
Lai, C.C.
Chiu, S.H.
關鍵字: crown-ethers
complexes
ions
axle
pseudopolyrotaxane
polyrotaxane
macrocycle
molecules
base
期刊/報告no:: Tetrahedron, Volume 65, Issue 14, Page(s) 2824-2829.
摘要: Die's-Alder reactions of the terminal alkyne units of SiO(2)-supported [2]pseudorotaxanes with 1,2,4,5-tetrazine derivatives proceed efficiently through solid-to-solid contact to provide both asymmetric and symmetric [2]rotaxanes incorporating either 24- or 25-membered-ring macrocycles. (C) 2009 Elsevier Ltd. All rights reserved.
URI: http://hdl.handle.net/11455/71415
ISSN: 0040-4020
文章連結: http://dx.doi.org/10.1016/j.tet.2008.12.082
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