請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/71435
標題: The enhancement of enantioselectivities for lipase-catalyzed reactions by using carbamates
作者: Lin, G.
Lin, W.Y.
Shieh, C.T.
關鍵字: pancreatic cholesterol esterase
azeotropic distillation
transacylation
reaction
organic-synthesis
inhibition
resolution
enzymes
期刊/報告no:: Tetrahedron Letters, Volume 39, Issue 48, Page(s) 8881-8884.
摘要: The enantioselectivity of porcine pancreatic lipase-catalyzed resolution of 1-indanol was enhanced up to 3 fold in the presence of carbamates. The optimum incubation time for 4-nitrophenyl-N-hexyl carbamate and the enzyme was 18 h before this biocatalytic resolution. The optimum concentration of the inhibitor 4-nitrophenyl-N-hexyl carbamate in this resolution was 1 % mole equivalent of the substrate 1-indanol. (C) 1998 Elsevier Science Ltd. All rights reserved.
URI: http://hdl.handle.net/11455/71435
ISSN: 0040-4039
文章連結: http://dx.doi.org/10.1016/s0040-4039(98)02021-8
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