Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/84978
標題: Microwave-Assisted Efficient Synthesis of Aryl Thioethers Through CH Functionalization of Arenes
關鍵字: Microwave
Aryl thioether
Iridium
Copper
CH functionalization
Arene
摘要: Microwave-assisted iridium-catalyzed meta C-Hborylation followed by copper-promoted C-S bond couplingreactions in one-pot is reported. This approach enables thesyntheses of aryl thioethers in short reaction times (within 2.5h). The system shows good functional group compatibility, aschloro, trifluoromethyl, fluoro and pyridine groups aretolerated by the reaction conditions. Both aryl- and alkyl thiolsare coupled smoothly. The products were formed with excellentregioselectivity in meta position.
URI: http://hdl.handle.net/11455/84978
文章連結: http://dx.doi.org/10.1055/s-0033-1339666
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