Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/85007
標題: A General Procedure for the Regioselective Synthesis of Aryl Thioethers and Aryl Selenides Through C–H Activation of Arenes
關鍵字: Sulfur
Selenide
C–H activation
Arenes
Iridium
Copper
摘要: A general procedure for the synthesis of aryl thioethers and aryl selenides in one-pot through sequential iridium-catalyzed C–H borylation and copper-promoted C–S and C–Se bond formation is described. Functional groups including chloro, nitro, fluoro, trifluoromethyl, and nitrogen-containing heterocycles were all tolerated under the reaction conditions. Importantly, not only aryl thiols and selenides but also their alkyl analogs were suitable coupling partners, and the products were obtained in good yields with high meta regioselectivity.
URI: http://hdl.handle.net/11455/85007
文章連結: http://dx.doi.org/10.1002/ejoc.201300248
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