Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/90529
標題: Fabrication and characteristics of P3HT solid-state Pb-Bi-S semiconductor-sensitized solar cells
P3HT固態Pb-Bi-S半導體敏化太陽能電池的製作與特性
作者: Chih-Hui Hsu
許志暉
關鍵字: Pb-Bi-S
Pb-Bi-S
引用: [1] B. O'regan, M. Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 353, 737-740 (1991). [2] Md. K. Nazeeruddin, F. D. Angelis, S. Fantacci, A. Selloin, G. Viscardi, P. Liska, S. Ito, B. Takeru, M. Grätzel, Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers, Journal of the American Chemical Society, 127, 16835-16847 (2005). [3] J. Hu, B. Deng, C. Wang, K. Tang, Y. Qian, Convenient hydrothermal decomposition process for preparation of nanocrystalline mineral Cu3BiS3 and Pb1−xBi2x/3S, Materials Chemistry and Physics, 78, 650–654 (2003). [4] V. Balasubramanian, N. suriyanarayanan, Preparation and characterization of novel single-crystalline PbBiS2 thin films, Materials Letters, 91, 362-364 (2013). [5] A. Yella, H. W. Lee, H. N. Tsao, C. Yi, A. K. Chandiran, M. K. Nazeeruddin, E. W. Diau,C. Y. Yeh, S. M. Zakeeruddin, M. Grätzel, Porphyrin-Sensitized Solar Cells with Cobalt (II/III)-Based Redox Electrolyte Exceed 12 Percent Efficiency, Science, 334, 629 (2011). [6] M. M. Lee, J. Teuscher, T. Miyasaka, T. N. Murakami, H. J. Snaith, Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites, Science, 338, 643-647 (2012). [7] 陳佳靜, 國立中興大學物理所碩士論文 (2008). [8] AuttasitTubtimtae, 國立中興大學物理學研究所博士學位論文 (2011). [9] M. Grätzel, review article Photoelectrochemical cells, Nature, 414, 338−344 (2001). [10] 林義成, 國立彰化師範大學機電系/顯示所 (2005). [11] A. J. Nozik, Quantum dot solar cells, Physica E: Low-dimensional Systems and Nanostructures, 14, 115-120 (2002). [12] 陳俊太,許千樹, TCIA台灣化學科技產業會刊 第十期 (2012). [13] C. J. Stolle, T. B. Harvey, B. A. Korgel, Nanocrystal photovoltaics: a review of recent progress, Current Opinion in Chemical Engineering, 2, 160–167 (2013). [14] S. H. Choi, H. Song, I. K. Park, J. H. Yum, S. S. Kim, S. Lee, Y. E. Sung, Synthesis of size-controlled CdSe quantum dots and characterization of CdSe–conjugated polymer blends for hybrid solar cells, Journal of Photochemistry and Photobiology A: Chemistry, 179, 135-141 (2006). [15] R. D. Schaller, V. I. Klimov, High Efficiency Carrier Multiplication in PbSe Nanocrystals: Implications for Solar Energy Conversion, Physical Review Letters, 92, 18 (2004). [16] 蔡進譯, 物理雙月刊二十七卷五期 (2005). [17] 陳頤承, 郭昭顯, 陳俊亨, 工業材料雜誌258期 (2008). [18] 蔡進譯, 物理雙月刊二十七卷五期 (2005). [19] L. Kavan, M.Grätzel, Highly efficient semiconducting TiO2 photoelectrodes prepared by aerosol pyrolysis, Electro chimica Acta, 40, 643-652 (1995). [20] H. J. Snaith, M.Grätzel, The Role of a 'Schottky Barrier' at an Electron-Collection Electrode in Solid-State Dye-Sensitized Solar Cells, Advanced Materials, 18, 1910-1914 (2006). [21] 林麗娟, 工業材料86期 (1994). [22] U. Bach, D. Lupo, P. Comte, J. E. Moser, F.Weissortel, J. Salbeck, H. Spreitzer, M. Grätzel, Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies, Nature, 395, 583-585 (1998).
摘要: 本研究主題為固態Pb-Bi-S半導體敏化太陽能電池,研究主要可分為兩部分:(1)先使用水熱法製作出半導體材料Pb-Bi-S粉末。(2)再進行主題Pb-Bi-S敏化太陽能電池的研究。固態太陽能電池的製程依序為噴霧熱解法合成blocking-layer,接著spin-coating多孔隙TiO2薄膜,接下來將Pb-Bi-S粉末混合PEG後,在TiO2表面分別鍍上Pb-Bi-S半導體做為敏化劑,最後填充P3HT,在表面形成over layer並濺鍍金電極。完成後的樣品利用X-ray粉末繞射儀,分析所合成出材料的相態為Pb_0.89 Bi_0.22 S_1.22,使用冷場發射掃描電子顯微鏡分析斷面結構,功率轉換效率分析太陽能電池的光電轉換效率。表現最佳的Pb-Bi-S半導體敏化太陽能電池,在21%的太陽光下,效率為0.008%,短路電流0.015 mA/cm2,開路電壓0.29V,填充因子40.07%。
This thesis presents solid-state Pb-Bi-S semiconductor-sensitized solar cells. Pb-Bi-S semiconductor powder was synthesized by the hydrothermal method. The solid-state solar cell was fabricated layer by layer as described below. First, a blocking layer was deposited on FTO by the hot-spray method. Then, a mesoporous-TiO2 layer was spin-coated above the blocking layer, followed by depositing the mixed Pb-Bi-S powder and PEG. The P3HT hole transport material was then filled into the mesoporous-TiO2 and formed an over-layer. Finally, an Au electrode was sputtered on the over-layer as the electron collector. X-ray powder diffraction the phase of the synthesized material is Pb_0.89 Bi_0.22 S_1.22. The morphology of the cell was analyzed by a field emission scanning electron microscope. I-V characteristics were measured by a Keithley 2400 source meter. The best Pb-Bi-S-sensitized solar cell yields a short circuit current of 0.0147 mA/cm2, an open circuit voltage of 0.29 V, a fill factor of 40.07% and a power conversion efficiency of 0.008 % under 21% illumination of AM 1.5 sun.
URI: http://hdl.handle.net/11455/90529
文章公開時間: 2018-07-30
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