請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/90593
標題: Aluminum Complexes Bearing [N,O]-Coumarin-Based Ligands : Synthesis, Characterization and Application in Ring-Opening Polymerization of Cyclic Ester
香豆素基底NO配位之鋁金屬催化劑的合成 鑑定及其對環酯類開環聚合之應用
作者: 陳筠
Yun Chen
關鍵字: coumarin
ring-opening polymerization
香豆素
開環聚合反應
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摘要: The coumarin-derived ligand precursors L1H-L8H have been prepared. Reactions of L1H-L8H with 1.2 equiv. of AlMe3 afford aluminum complexes 48-55. All compounds were characterized by NMR spectroscopy and elemental analysis. Molecular structures of 49, 51, and 52 were determined by X-ray crystallography. The catalytic activities of these complexes towards the ring-opening polymerization of cyclic esters in the presence of alcohols were also examined. Based on the homonuclear decoupled 1H NMR spectra, the atactic polylactides (Pm values ranged from 0.44 to 0.57) were produced using 48-55 as catalysts. Kenetics studies showed that the polymerization reaction is first-order for the complex 48.
成功製備香豆素衍生物配位前驅物L1H-L8H,並將配位前驅物L1H-L8H與1.2當量的三甲基鋁反應後可合成鋁錯合物48-55,所有化合物皆可經由核磁共振光譜與元素分析鑑定,其中鋁錯合物49、51、52成功得到晶體並以X-ray單晶繞射儀進行結構分析。 所有鋁錯合物催化劑在外加醇類的條件下對環酯類皆具有活性,以同核去耦合核磁共振氫光譜可發現,鋁錯合物48-55可合成出具atactic微結構的聚乳酸,動力學研究顯示鋁錯合物48在開環聚合反應中為一級反應。
URI: http://hdl.handle.net/11455/90593
文章公開時間: 2018-07-09
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