Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/90668
標題: The Development and Application of Planarized Disposable Screen-printed Carbon Electrodes
平整性可拋棄式網版印刷碳電極之研發與應用
作者: 馮俊方
Chun-Fang Feng
關鍵字: SPCE
Planarize
Catechin
Self-assembly
網版印刷碳電極
平整性
兒茶素
自我組裝
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摘要: The electrochemical detection method has attracted much attention compared to other methods that have been developed for detection of analyte due to its advantages like simple operational procedure, portable and cheap. In this work, we use ultrasonic polishing to get the planarized surface on the screen printed carbon electrode (SPCE). We represent ultrasonic polishing technique in SPCE that give planarized, cheap and disposable electrode for electrochemical analysis. This dissertation has comprised two parts of work. Firstly, we prepare the γ-Al2O3 modified electrode using γ-Al2O3 slurry by ultrasonic polishing technique. This modified electrode was used for detection of Catechin. The experimental results showed that detection of Catechin with the γ-Al2O3 modified electrode can provide a wide linear range (0.1- 10 μM), detection limit (15 nM) and good recoveries in real sample. The similar procedure was adapted to modify the electrode using SiO2 slurry to polish SPCE. The surface roughness of the electrode is similar to that of the GCE. The above modified electrode was utilized to fabricate glucose biosensor by self-assembly technique on planarized SPCE. The polished electrode will be useful for further electrode modification and analyte detection. It may emerge as a new platform to detect analyte in disposable electrode.
相較於其他分析手法,電分析化學具有操作簡便,維護成本低廉以及攜帶方便等優勢,因此,常應用於大量檢體中作為快速篩檢的方法。本論文主要利用超音波拋光技術應用於網版印刷碳電極(screen-printed carbon electrode, SPCE),期望藉由電極表面形貌的改變以提升電極應用廣度。 本論文分成兩大部分,第一部分是利用超音波機械拋光修飾γ Al2O3於電極表面並應用於偵測兒茶素,從分析結果可知修飾電極對於兒茶素的偵測具有良好的線性範圍與穩定性,且可應用於真實樣品檢測中。 第二部分,同樣利用超音波機械拋光的技術研磨電極表面,使SPCE電極粗糙度下降接近於GCE的粗糙度,並利用拋光修飾後的電極應用於自組裝葡萄糖生物感測器的研究。 綜觀而言,本研究主要結合超音波機械拋光技術與可拋棄式網版印刷碳電極SPCE之兩項個別優勢,開發出具有平整性、價格低廉與可拋棄性的碳基材工作電極平台應用於電分析領域中。
URI: http://hdl.handle.net/11455/90668
文章公開時間: 2017-07-01
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