Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/90673
標題: 1. Microwave-Promoted Rhodium-Catalyzed Carbon-Sulfur Bond Cross-Coupling Reaction In Water 2. Yttrium-Catalyzed Carbon-Sulfur Bond Cross-Coupling Reaction
1.微波促進水相銠金屬催化碳-硫鍵之交互耦合反應 2.釔金屬催化碳-硫鍵交互耦合反應
作者: 吳佳蓁
Chia-Chen Wu
關鍵字: no
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摘要: In the first part of this thesis, we report that a combination of rhodiumsalt with DPPE can be served as a powerful catalyst for microwave-promoted coupling of thiols with iodides in water. The second part of this thesis, we investigate a yttrium-catalyzed cross-coupling reaction of this with aryl iodides by using bathophenanthroline as ligand. Remarkably, it is the first example of yttrium catalyzed C-S bond formation process.
本論文第一部分為探討銠金屬搭配 1,2-雙(二苯基膦)乙烷(DPPE),以水為溶劑,使用微波加熱裝置促進芳香基碘化物與硫醇之交互耦合反應。 第二部分則是探討釔金屬搭配 4,7-二苯基-鄰二氮菲,進行芳香基碘化物與芳香基硫醇的碳-硫鍵生成反應。這是釔金屬被發現可以促進碳-硫鍵交互偶合反應的弟一個例子。
URI: http://hdl.handle.net/11455/90673
文章公開時間: 2018-07-16
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