請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/90676
標題: The application of annealed barrel-plating nickel electrode in electroanalysis
拋棄式鍛燒滾鍍鎳電極之製備與應用
作者: 翁鈺鼎
Yu-Ting Weng
關鍵字: barrel-plating Nickel Electrode
Ni-Cu BPE
hydrazine
sulfide
滾筒電鍍鎳電極
鎳銅雙金屬
聯胺
硫化物
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摘要: The development and application of barrel-plating Nickel Electrode (designated as NiBPE) in the detection of different electroactive species are demonstrated in this study. The electrodes coated by high-cost metal material has good specific and catalytic ability, but its high cost due to be hardly to apply the disposable electrode like screen printed electrode. This Ni-Cu BPE was prepared from a NiBPE by manipulating the grain boundary diffusion through thermal annealing treatment and electrochemical activation in alkaline solution. In first part, based on a more detail XRD study, we tend to explain how copper is diffused to the electrode surface. Nickel and copper electrodes for electrochemical analysis of the characteristics of the material, and the show remained highly electrically active electrode. In second part, We further demonstrated its application as an electrochemical sensor towards non-enzymatic detection of hydrazine with good selectivity. The sensitivity for hydrazine detection using cyclic voltammetry was found to a low peak potential of ~0.2 V vs. Ag/AgCl in alkaline medium. Real sample analysis was successfully demonstrated for the detection of hydrazine in environmental water samples. In third part, the Ni-Cu BPE showed with a low detection limit of sulfide. Due to the adsorption of the sulfide can effectively pick out from the complex matrices, and good interference and real sample test appear its application.
本研究以滾筒電鍍鎳電極作為電極基材,利用滾筒電鍍鎳電極具備成本低廉、大量製作、使用便捷之優點,且可以在短時間內以高溫鍛燒的方式大量製備鎳銅雙金屬氧化物電極(Ni-Cu BPE),對於分析物之偵測亦有極佳靈敏度與選擇性。第一部分針對電極之物性及其電化學性質探討,藉由 X-光繞射光譜儀證實銅元素擴散的推論,深入了解電極組成,且對於後續之研究有很大的幫助。第二部分是將鎳銅雙金屬氧化物電極應用鹼性環境下(pH = 13)於偵測聯胺之研究,研究中發現不僅降低偵測聯胺時所施加的電位並有效提升電極對於聯胺之靈敏度及選擇性,以便能利用流動注入分析的方式對於真實樣品進行分析。第三部分是將鎳銅雙金屬氧化物電極應用於硫化物之偵測,有別於一般修飾電極繁瑣且困難的製備過程,鎳銅雙金屬氧化物電極透過簡單的製程即可對硫化物進行偵測,因吸附作用可有效將硫化物由複雜基質中挑選而出,展現出實際應用的可能性。
URI: http://hdl.handle.net/11455/90676
文章公開時間: 2017-06-23
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