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標題: 丙二醇甲醚之純化程序設計與最佳化研究
The Optimal Process Design of Propylene Glycol Monomethyl Ether
作者: Ming-Wei Lin
關鍵字: propylene glycol monomethyl ether
process design
total annual cost
引用: [1]许铭案, 郭光埌, 蔡牧霖, 戴杏如, 'Resist cleaning agents', CN Patent, No.1,800,988 B, 2010. [2]杨旭忠, 张勇, 周子牛, 路涛, 'Method for preparing electronic grade propylene glycol monomethyl ether', CN Patent, No. 101,613,259 B, 2013. [3]Dana Durham, 'Photoresist treating composition consisting of a mixture of propylene glycol alkyl ether and propylene glycol alkyl ether acetate', U.S. Patent, No. 4,983,490 A, 1991. [4]William C. Nelson, Octavia Lehar, 'Use of mixtures of ethyl lactate and N-methyl pyrollidone as an edge bead remover for photoresists', U.S. Patent, No. 5,814,433, 1998. [5]Mitsuru Sato, Naomi Nagatsuka, Koichi Nagasawa, Hutoshi Shimai and Kouji Harada, 'Method for the pre-treatment of a photoresist layer on a substrate surface', U.S. Patent, No.5849467 A, 1998. [6]Jun Koshiyama, Futoshi Shimai and Hidehito Fukushima, 'Remover solvent for partial removal of photoresist layer', U.S. Patent,No.6,117,623 A, 2000. [7]Joseph E. Oberlander, Craig Traynor,Ernesto S. Sison, Jeff Griffin, 'Edge bead remover for thick film photoresists', U.S. Patent, No. 6,524,775 B1, 2003. [8]W. L. McCabe and E. W. Thiele, “Graphical design of fractionating columns,” Industrial & Engineering Chemistry, Vol. 17, No. 6, pp. 605-611, 1925. [9]W. L. McCabe, J. C. Smith and P. Harriott, Unit Operations of Chemical Engineering, 6th Ed., McGraw-Hill Book Co., New York, pp. 154, 2001. [10] R. Taylor and A. Lucia, “Modeling and analysis of multicomponent separation processes,” A.I.Ch.E. Symposium Series, vol. 91, No. 304, pp. 19-28, 1995. [11] R. Taylor, R. Krishna,. “Modelling reactive distillation,” Chemical Engineering Science, vol. 55, No. 22, pp 5183-5229, 2000. [12]E.C.Carlson, “Don’t Gamble with Physical Properties for Simulations,” Chemical engineering progress, vol. 92, No. 10, pp. 35-46. [13]Katsumi Tochigia, Hideyuki Takaharaa, Yoshinori Shigaa, and Yasuto Kawaseb,. “Isobaric vapor–liquid equilibria for water + propylene glycol monomethyl ether (PGME), water + propyleneglycol monomethyl ether acetate (PGMEA), and PGME + PGMEA at reduced pressures,” Fluid Phase Equilibria, Vol. 260, NO. 1, pp. 65–69, 2007. [14]H.Renon,Prausnitz and J.M.Local, “Compositions in Thermodynamic Excess Functions for Liquid Mixtures,” AIChE J, vol. 14, No. 1, pp. 135-144, 1968. [15]D. S.Abrams, J. M. Prausnitz, “Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Free Energy of Partly or Completely Miscible Systems,” AIChE J, vol. 21, No. 1, pp. 116-128, 1975. [16]J. G. Hayden, J. P. O’Connell, “A Generalized Method for Predicting Second Virial Coefficients,” Industrial & Engineering Chemistry Process Design and Development, vol. 14, No. 3, pp. 209-216, 1975. [17]F. W.Winn, “New relative volatility method for distillationn calculations,” Petrol. Refin, vol. 37, No. 5, pp. 216, 1958. [18] YANG De-ming,WANG Yang,LIAO Qiao, “Simulation of separation for 2-methoxyethanol-water system by separate heat pump distillation,” Chemical Engineering(China), 2012. [19] J.M. Douglas, Conceptual design of chemical process, McGraw-Hill, New York, 1988. [20] S.F. Chiang, C.L. Kuo, C.C. Yu, D.S.H. “Wong. Design alternatives for the amyl acetate process: Coupled reactor/column and reactive distillation,” Ind Eng Chem Res, vol. 41, No. 13, pp. 3233-3246, 2002. [21] T.R. Elliott, W.L. Luyben, “Quantitative assessment of controllability during the design of a ternary system with two recycle streams,” Ind Eng Chem Res, vol. 35, No. 10, pp. 3470-3479, 1996.
摘要: 本研究利用模擬軟體Aspen plus對光阻稀釋劑進行純化而得丙二醇甲醚(propylene glycol monomethyl ether,PM)再回收利用於工業上,進行純化之製程模擬與設計層面探討。首先選擇合適的熱力學模式,由於本論文是許多成分的非理想系統,故熱力學模式選擇液相活性係數法中的NRTL與Hayden-O’Connell狀態方程式來做運算更能貼近真實情況。在此模擬系統過程中,是以平衡板(equilibrium stage)的概念假設各平衡板之汽相與液相的流動均達到熱力學相平衡。並提出了兩個純化系統架構,其中蒸餾塔(1)用於脫水,蒸餾塔(2)用於純化丙二醇甲醚與丙二醇甲醚醋酸酯。 使得整體蒸餾程序一天可得30頓丙二醇甲醚且濃度高於99.7%以上,使之具有超高潔淨純度及超低水分之電子級丙二醇甲醚。並同時更改內部規格ex:總塔板、進料位置、進料流率來探討最小年度總成本(Total Annual Cost,TAC),以進行優化設計。
This study comprises the design of distillation processes for solvent recycling with Aspen Plus. Propylene glycol monomethyl ether (PM) is separable from thinner by distillation. Raw material includes alcohol, ethers and esters.This study comprises the design of distillation processes for solvent recycling with Aspen Plus. Propylene glycolmonomethyl ether (PM) is separable from thinner by distillation. Raw material includes alcohol, ethers and esters. NRTL activity coefficient and Hayden-O’Connell state equation are chosen to model the real situation with good accuracy. In this simulation system two distillation columns are employed. The first distillation columns is designed to remove water and the second distillation columns is used to separate PM and propylene glycol monomethyl ether acetate (PMA) This process produces PM higher than 99.7% in mass composition and 30 tons a day in capability. High purity of PM finds its application in cleaner of electronic material. This study is aiming at optimizing the design. Design parameters includes the number of tray, the feed tray locations and feed flow rates based on the total annual cost (TAC).
其他識別: U0005-1308201516024000
文章公開時間: 10000-01-01
Appears in Collections:化學工程學系所



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