請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/91617
標題: 以Fenton法及Photo-Fenton法降解含磺胺甲基噁唑之廢水
Degradation of Sulfamethoxazole waste water by Fenton and Photo-Fenton processes
作者: Pin-Chia Chiu
邱品嘉
關鍵字: Photo-Fenton
抗生素
廢水處理
Photo-Fenton oxidation process
Antibiotic
Wastewater treatment
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摘要: 高級氧化程序(Advanced oxidation processes, AOPs)是一種能夠產生高氧化力且非選擇性的氫氧自由基(Hydroxyl radical,.OH)的程序,利用氫氧自由基有效的降解水中各種有機物。本研究以磺胺甲基噁唑(Sulfamethoxazole , SMX)抗生素作為目標污染物,初始濃度為10mg/L,控制不同參數(H2O2濃度、Fe2+濃度、光強度等),利用四種氧化程序紫外光/過氧化氫(UV/H2O2)、亞鐵離子/過氧化氫(Fenton)、紫外光/亞鐵離子/過氧化氫(Photo-Fenton)、紫外光/亞鐵離子/過氧化氫/活性碳(Photo-Fenton/AC),對廢水中SMX以及化學需氧量(COD)去除,使其對環境危害降至最低。 研究結果顯示,Fenton 程序之最適操作條件為:pH = 3 、 [H2O2]/[Fe2+]莫耳比 = 10 ([H2O2]/[Fe2+] = 0.59/0.059 mM、[H2O2]/[SMX] 莫耳比 = 15)。Photo-Fenton 程序之最適操作條件為:光強度 = 90W、pH = 3、[H2O2]/[Fe2+]莫耳比 = 10 ([H2O2]/[Fe2+] = 0.59/0.059 mM、[H2O2]/[SMX] 莫耳比 = 15)。Photo-Fenton/AC程序之最適操作條件為:光強度 = 90W、pH = 3、[H2O2]/[Fe2+]莫耳比 = 10 ([H2O2]/[Fe2+] = 0.59/0.059 mM、[H2O2]/[SMX]莫耳比 = 15、[AC]=0.01 g/L)。以 UV/H2O2、Fenton、Photo-Fenton 、Photo-Fenton/AC四種程序之最佳條件處理120分鐘後,廢水中之 SMX 之去除率分別為15.2%、78.9%、82.4%、80.0%;COD 降解部分,其去除率為10%、44.4%、60%、66.7%。雖然Photo-Fenton的SMX去除率比Photo-Fenton/AC好,但是Photo-Fenton/AC有較好的COD去除率。
Advanced oxidation processes (AOPs) can produce strong oxidation ability, with non-specific hydroxyl radical (.OH), which can effectively decompose a variety of organic pollutants in the wastewater. The study pollutant initial concentration is 10 mg/L to target, and adjustment different parameter (H2O2 concentration, Fe2+ concentration, light intensity) to investigate the removal and chemical oxygen demand (COD) of Sulfamethoxazole(SMX) antibiotic by UV/H2O2, Fenton, Photo-Fenton and Photo-Fenton/AC systems. Hope that it will reduce environmental imparement. The optimum operating conditions for Fenton process in this study were as follows : pH = 3, [H2O2]/[Fe2+] molar ratio = 10 ([H2O2]/[Fe2+] = 0.59/0.059 mM, [H2O2]/[TX-100] molar ratio = 15); for Photo-Fenton process in this study was as follows : UV light intensity = 90 W, pH = 3, [H2O2]/[Fe2+] molar ratio = 10 ([H2O2]/[Fe2+] = 0.59/0.059 mM, [H2O2]/[TX-100] molar ratio = 15); for Photo-Fenton/AC process in this study was as follows : UV light intensity = 90 W, pH = 3, [H2O2]/[Fe2+] molar ratio = 10 ([H2O2]/[Fe2+] = 0.59/0.059 mM, [H2O2]/[TX-100] molar ratio = 15, [AC]=0.01g/L). The removal of SMX wastewater with UV/H2O2, Fenton, Photo-Fenton and Photo-Fenton/AC processes 120 minute were 15.2%, 78.9%, 82.4%, and 80.0% respectively. And COD removal rates were 10%, 44.4%, 60% , and 66.7% respectively. The SMX removal rate of Photo-Fenton is better than that of Photo-Fenton/AC; however, Photo-Fenton/AC has better COD removal rate than Photo-Fenton.
URI: http://hdl.handle.net/11455/91617
文章公開時間: 2017-07-14
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