Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/94941
標題: Synthesis of (±)-Aphanorphine Using Rh-Catalyzed Cyclohydrocarbonylation
作者: Chiou, Wen-Hua
Chen, Po-Chou
關鍵字: Benzazepines
Bridged-Ring Compounds
Catalysis
Molecular Structure
Naphthalenes
Organometallic Compounds
Pyrroles
Rhodium
Stereoisomerism
摘要: A facile formal synthesis to aphanorphine and its analogue is described, featuring Rh-catalyzed cyclohydrocarbonylation of 2-aminodihydronaphthalene to the bridged benzazepine core. Subsequent introduction of the methyl group and functional group transformation complete the synthesis of aphanorphine and its analogue over eight steps.
URI: http://hdl.handle.net/11455/94941
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