Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/95607
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dc.contributor.author黃智峯zh_TW
dc.contributor.authorChih-Feng Huangzh_TW
dc.contributor.authorMiao-Jia Chenzh_TW
dc.contributor.authorChing-Hsuan Linzh_TW
dc.contributor.authorYeo-Wan Chiangzh_TW
dc.date2017-05-13-
dc.date.accessioned2018-10-12T01:48:42Z-
dc.date.available2018-10-12T01:48:42Z-
dc.identifier.urihttp://hdl.handle.net/11455/95607-
dc.description.abstractWe synthesized a series of copolybenzamides (PBA) through chain-growth condensation polymerization (CGCP) of 4-(octylamino)benzoate (M4OB) and methyl 3-(4-(octyloxy)benzylamino) benzoate (M3OOB) co-monomers. Well-defined copolybenzamides with close to theoretical molecular weights (Mn ≈ 10,000–13,000) and narrow molecular weight distributions (Mw/Mn < 1.40) were obtained. Selective removals of the protecting group (i.e., 4-(octyloxy)benzyl group) from the affording P(M3OOB-co-M4OB) copolybenzamides were subsequently performed to obtain P(M3NH-co-M4OB) copolymers. These novel N-H-containing copolybenzamides (named as PNHBA) can not only provide hydrogen bonds for polymer-polymer blends but also have good solubility in organic solvents. Miscibility of the PNHBA and Nylon 6 blends was investigated by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), FT-IR, contact angle analysis, transmission electron microscope (TEM), and dynamic mechanical analysis (DMA). This study illustrates a novel type of copolybenzamide with controlled molecular weight and narrow molecular weight distribution through an effective synthetic strategy, and can be applied to a practical blend of Nylon 6 with good miscibility. (PDF) Synthesis of Well-Defined Poly(N-H Benzamide-co-N-Octyl Benzamide)s and the Study of their Blends with Nylon 6. Available from: https://www.researchgate.net/publication/316949419_Synthesis_of_Well-Defined_PolyN-H_Benzamide-co-N-Octyl_Benzamides_and_the_Study_of_their_Blends_with_Nylon_6 [accessed Oct 12 2018].zh_TW
dc.language.isoen_USzh_TW
dc.publisherPOLYMERSzh_TW
dc.relationPolymers, May 2017, 9(5):172zh_TW
dc.subjectchain-growth condensation polymerizationzh_TW
dc.subjectpolybenzamidezh_TW
dc.subjectNylon 6zh_TW
dc.subjectpolymer blendszh_TW
dc.titleSynthesis of Well-Defined Poly(N-H Benzamide-co-N-Octyl Benzamide)s and the Study of their Blends with Nylon 6zh_TW
dc.typeJournal Articlezh_TW
dc.identifier.doi10.3390/polym9050172zh_TW
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