Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/96298
標題: 1.Investigation of Multinuclear Copper Complexes in C-S Bond Cross-Coupling Reaction 2.Synthesis and Application of Squaraine Rotaxanes
1.多核銅金屬錯合物在碳-硫鍵耦合反應的研究 2.合成具方酸結構之輪烷及其應用
作者: Nien-Chi Chang Liao
張廖年旂
關鍵字: 銅金屬錯合物
碳-硫
方酸
輪烷
Copper Complexes
C-S Bond
Squaraine Rotaxanes
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摘要: Aryl thioethers are widely found in biochemistry and pharmaceutical chemistry, which can be easily synthesized through transition metal catalyzed cross-coupling reaction. In the first part of this thesis, we report the synthesis of thioether via copper complex-catalyzed cross-coupling of aryl iodides with thiols. Due to the shortage of fossil fuels, development of alternative energy source is inevitable. At present, solar source looks promising as a renewable energy source. In the second part this thesis, we report the synthesis and characterization of squaraine derivatives and squaraine rotaxanes for organic photovoltaic device.
芳香基硫醚的結構廣泛存在於生物化學與藥物化學中,常見的合成方法為利用過渡金屬催化交互耦合反應。論文的第一部分,我們利用銅金屬錯合物促使芳香基碘化物與硫醇進行交互耦合反應,生成硫醚化合物。 由於全球石化能源短缺,開發替代方案刻不容緩,其中太陽能為最具潛力之再生能源。論文的第二部分,我們成功合成方酸衍生物與具方酸結構之輪烷並進行光學與電化學性質分析,最終應用於太陽能電池光電轉換效率測試。
URI: http://hdl.handle.net/11455/96298
文章公開時間: 2018-08-08
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