Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/96320
標題: 1.Investigation of Blue LEDs Promoted Synthesis of Dithioacetals 2.Investigation of Blue LEDs Promoted Formation of C-S Bond of Aryl Amines with Thiols
1.藍色發光二極體促進二硫縮醛合成之研究 2.藍色發光二極體促進芳香胺與硫醇生成碳—硫鍵之研究
作者: Kai Du
杜凱
關鍵字: 藍色發光二極體促進反應
二硫縮醛化
曙紅Y
光催化
硫醚
Blue LEDs-promoted reaction
Dithioacetalization
Eosin Y
Photocatalysis
Thioether
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摘要: In the first part of this thesis, we achieve a simple and elegant method for dithioacetalization of aldehyde using blue LEDs irradiation under photochemical reaction. The salient features of this method are broad substrate scope and good tolerance of electron donating and withdrawing group, metal free and solvent free conditions. It is noteworthy that our present protocol is eco-friendly in nature and we will develop LEDs promoting reaction in future green chemistry avenues. In the second part of this thesis, we achieve a simple method for thiol ether formation of aryl amines and thiols using blue LEDs irradiation under photochemical reaction. This project is metal free, solvent free and eco-friendly in nature.
本論文中的第一部分,利用藍色發光二極體來誘導曙紅Y催化醛與硫醇進行硫縮醛化的反應,僅需要微量的曙紅Y,在不需過渡金屬及溶劑的條件下可進行縮硫醛反應,此系統可容忍多樣化的官能基,無論是推拉電子或雜環類分子,都能得到不錯的產率,是一個對環境友善的系統。 第二部分,我們利用藍色發光二極體誘導曙紅Y,在亞硝酸叔丁酯作用下,使芳香基胺化合物與硫醇類化合物進行碳—硫鍵生成,在不需過渡金屬及溶劑的條件下,得到芳香基硫醚化合物。
URI: http://hdl.handle.net/11455/96320
文章公開時間: 2019-08-07
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