請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/96333
標題: Synthesis, Structural Characterization and Magnetic Properties of Mononuclear and Polynuclear Lanthanide Complexes by Using Schiff-Base Ligands with Different Electron-Donation Group and Electron-Withdrawing Group
經修飾推拉電子基之希夫鹼配位基合成單核及多核鑭系錯合物之合成、結構鑑定與磁性性質研究
作者: Jun-Yu Wei
魏俊育
關鍵字: 希夫鹼配位基
單分子磁鐵
Schiff-base ligands
Single molecule magnets
引用: 1. J. M. Frost, K. L. M. Harriman and M. Murugesu, Chem. Sci., 2016, 7, 2470-2491. 2. 杜怡君、張毓娟、翁乙壬、蘇怡帆、陳世毓、梁哲銘、蕭巧雯、吳信璋、卓育珉,磁性基本特性及磁性材料應用 3. H. Adawi, ResearchGate, 2016 4. T. Mori, Electronic Properties of Organic Conductors., 2016 5. C. J. Kuo, 6. R. J. Holmberg and P. H. Lin, Dalton Trans., 2015, 44, 19758-19762. 6. R. J. Holmberg, C. J. Kuo, B. Gabidullin, C. W. Wang, R. Clérac, M. Murugesu and P. H. Lin, Dalton Trans., 2016, 45, 16769-16773. 7. T. Lis, Acta Cryst., 1980, B36, 2042-2046. 8. R. Sessoli, H. L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K.Folting, D. Gatteschi, G.Christou and D. N. Hendrickson, J. Am. Chem.Soc., 1993, 115, 1804-1816 9. N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara and Y. Kaizu, J. Am. Chem. Soc., 2003, 125, 8694-8695. 10. B. Joarder, S. Mukherjee, S. Xue, J. Tang and S. K. Ghosh, Inorg. Chem., 2014, 53, 7554-7560. 11. J. Tang, I. Hewitt, N. T. Madhu, G. Chastanet, W. Wernsdorfer, C. E. Anson, C. Benelli, R. Sessoli and A. K. Powell, Angew. Chem., Int. Ed., 2006, 45, 1729–1733. 12. M. T. Dumas, G. P. Chen, J. Y. Hu, M. A. Nascimento, J. M. Rawson, J. W. Ziller, F. Furche, W. J. Evans, J. Organomet. Chem., 2017, 849–850 38-47. 13. L. Zhang, P. Zhang, L. Zhao, J.F. Wu, M. Guo and J. Tang, Inorg. Chem., 2015, 54, 5571-5578. 14. B. S. Dolinar, D. I. Alexandropoulos, K. R. Vignesh, T. James and K. R. Dunbar, J. Am. Chem. Soc., 2018, 140, 908-911. 15. I. F. Díaz-Ortega, J. M. Herrera, T. Gupta, G. Rajaraman, H. Nojiri, E. Colacio, Inorg. Chem., 2017, 56, 5594–5610. 16. 郭哲榮, 以希夫鹼配位基合成雙核、六核、九核、和十六核鑭系金屬團簇之磁性性質探討, 2016. 17. 王家偉, 以希夫鹼配位基合成多合鏑和銅金屬錯合物之合成、結構鑑定與磁性/催化應用, 2017. 18. 劉芸廷, 新穎含胺基雙苯並三唑苯酚氧基及硝基苯酚基與希夫鹼之鏑與釔金屬錯合物合成、結構鑑定及催化性質與磁性性質之研究, 2017. 19. P. H. Lin, T. J. Burchell, R. Clérac and M. Murugesu, Angew. Chem., Int. Ed., 2008, 47, 8848-8851. 20. J. Cirera, E. Ruiz and S. Alvarez, Organometallics, 2005, 24, 1556-1562. 21. N. F. Chilton, D. Collison, E. J. L. McInnes, R. E. P. Winpenny and A. Soncini, Nat. Chem., 2013, 4, 2551. 22. Y. Yanagisawa, Y. L. Nan, K. Okuro and T. Aida, Science, 2018, 359, 72-76. 23. P. H. Lin, I. Korobkov, T. J. Burchell and M. Murugesu, Dalton Trans., 2012, 41, 13649-13655.
摘要: In this research, five kinds of Schiff-Base ligands are ultilized to synthesize sixteen complexes. Three polynuclear complexes are synthesized by ligand H3bsc. Complex(2) and complex(3) are novel octanuclear structure. Then, two Schiff-Base ligands with Different Electron-Donation Group (H-hmni) and Electron-Withdrawing Group (H-hdnb) generate nine mononuclear complexes. From complex(4) to complex(12) are mononuclear complexes. Complex(4)and complex(8) are isostructural complexes as well as complex(6) and complex(10). Finally, H-hmnoi and (H3dnoc) are ultilized to synthesize mononuclear and trinuclear complexes, respectively. Complex(14), (15), (16) have Single-Molecule Magnet behavior.
在本次研究中,以五個希夫鹼配位基來合成十六個錯合物。以配位基H3bsc合成三個多核錯合物,分別為五核錯合物(1)以及八核錯合物(2)、(3),其中八核錯合物是新穎的八核結構。以含有推拉電子基的配位基H-hmni, H-hdnb合成九個單核錯合物,其中錯合物(4)與錯合物(8)以及錯合物(6)與錯合物(10)互為等結構的錯合物,兩組晶體結構只有配位基的不同。而在配位基H-hmnoi以及H3-hdnoc的研究中,利用這兩種單邊及雙邊的配位基,來分別合成單核的錯合物(13)、(14)、(15)以及以三角形為核心結構的三核錯合物。其中錯合物(14)、(15)、(16)具有單分子磁鐵的性質。
URI: http://hdl.handle.net/11455/96333
文章公開時間: 2019-07-30
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