請用此 Handle URI 來引用此文件: http://hdl.handle.net/11455/96484
標題: 嶄新的二氧化鈦與硫化鎘混合塗膠製備的量子點敏化太陽能電池
Brand-New TiO2 & CdS Mixed Paste Based Quantum Dots-Sensitized Solar Cell
作者: 李晨右
Chen-Yu Li
關鍵字: 量子點太陽能電池
溶膠-凝膠
緻密層
逆微胞法
膠體
QDSCs
Sol-Gel
Compact Layer
Reverse Micelles
Paste
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摘要: 本實驗以溶膠-凝膠法製備出在pH=3~11不同酸鹼值環境下的二氧化鈦顆粒以及以逆微胞法合成出約5nm硫化鎘量子點。控制二氧化鈦與硫化鎘量子點不同的比例製作成TiO2與CdS均勻混合膠體,並應用於量子點敏化太陽能電池的光陽極。由I-V 量測發現pH=7製備的TiO2顆粒與CdS混合膠體製備的電池,由於其CdS量子點易吸附於TiO2上,獲得2.47mA/cm2電流密度、0.68V開路電壓與超過0.8%最佳的光電轉換效率。經由SEM 與EDX Mapping發現,本製程可以明顯改善之前本實驗室直接由溶凝膠法製備產生TiO2經過熱處理後過度聚集成團塊,與量子點分佈不均勻的問題。電池樣品經由EIS量測分析其各界面電荷移動的機制。
In this study, titanium dioxide particles using different pH values ranging from 3 to 11 are prepared by sol-gel method, while, cadmium sulfide quantum dots with size about 5nm are synthesized by reverse micelles method. The photoelectrode paste of the quantum dot-sensitized solar cells are prepared by mixing of different ratio of TiO2 and CdS. The solar cell using the photoelectrode paste that is prepared with pH = 7 and TiO2/CdS=1 has the best performance. The photoelectric conversion efficiency of this cell is 0.8, and the short circuit current density is 2.47mA/cm2,, and the open circuit voltage equals to 0.68V. Ac impedance is employed to investigate the electron transport mechanism between the interfaces of the battery.
URI: http://hdl.handle.net/11455/96484
文章公開時間: 2017-08-04
顯示於類別:奈米科學研究所

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