Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/99256
標題: Low temperature de-oxidation for copper surface by catalyzed formic acid vapor
作者: Pei-Wen Chou
Jenn-Ming Song
宋振銘
Zong-Yu Xie
Masatake Akaike
Tadatomo Suga
Masahisa Fujino
Jing-Yuan Lin
關鍵字: Deoxidation
Formic acid vapor
Pt catalysts
FTIR
Kinetics
Hydrogen radical
摘要: This study investigated low temperature reduction of copper oxides using modified formic acid vapor treatment with Pt catalysts in terms of reaction kinetics and mechanisms. An in situ FTIR was adopted to monitor the evolution of organic ligands and oxidized copper surface under catalyzed formic acid vapor. 350 nm-thick Cu2O can be perfectly and efficiently transformed to pure copper at 160 °C. Analytical results of electron paramagnetic resonance verify that HCOOH can be easily decomposed and forms hydrogen radicals through catalysis with Pt. An optimal catalytic temperature of 150 °C which generated the maximum amount of hydrogen radicals was suggested.
URI: http://hdl.handle.net/11455/99256
文章連結: https://www.sciencedirect.com/science/article/pii/S0169433218317720
Appears in Collections:材料科學與工程學系

文件中的檔案:

取得全文請前往華藝線上圖書館



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.