Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/99503
標題: 高頻通訊用可交聯型磷系低介電聚氧二甲苯與以木質素為基質之高剛性氣體分離膜之合成與性質研究
Synthesis and properties of crosslinkable phosphinated low-dielectric polyphenylene oxide for high frequency communication and lignin-based high rigid gas separation membrane
作者: 谷祖強
Zu-Chiang Gu
關鍵字: 聚氧二甲苯
低介電
熱穩定性
環氧樹脂
氣體分離
木質素
熱穩定性
polyphenylene oxide
Low dielectric
High thermal property
Epoxy resin
Gas separation
lignin-based
High thermal property
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摘要: Part I : 本論文探討工程塑膠聚氧二甲苯(PPO)的改質與合成,一般聚氧二甲苯因製備時分子量過大導致於黏性太高難以加工,並且在使用時必須而外添加阻燃劑,但添加阻燃劑會使得工程塑膠的熱穩定性下降,所以本篇利用低分子量的聚氧二甲苯衍生物(SA90)經由溴化反應,導入溴原子關能基團,接著把具有阻燃效果的磷系單體(DOPO)導入於低分子量的聚氧二甲苯衍生物,其聚氧二甲苯主鍊具有阻燃的效果並且使用此種磷系單體可以使得聚氧二甲苯衍生物的熱穩定性上升。 將得到的聚氧二甲苯經由末端改直再藉由與環氧樹脂或是交聯劑(TAIC)固化後可得具有高玻離轉移溫度且低介電常數與損失以及低吸水性的工程塑膠聚氧二甲苯。 Part II : 薄膜分離技術廣泛應用於海水淡化,血液透析,以及氣體分離如O2/N2分離,CO2/CH4分離,以及H2/CH4分離等。薄膜分離不需經由相轉變即可進行分離,為一節省能源之程序。薄膜材料是決定氣體分離效果的主要因素,高的氣體穿透率及選擇率,良好的機械性質以及耐久性為重要的特性因此本實驗設計出由木質素提煉出來之香草醛單體來製備出高剛性氣體分離膜,已達到氣體分離的效果。
URI: http://hdl.handle.net/11455/99503
文章公開時間: 2020-07-28
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