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|標題:||Electrochemical Dehydrogenative Phosphorylation of Thiols||作者:||Chung-Yen Li
Daggula Mallikarjuna Reddy
We report herein a new approach for the synthesis of organothiophosphates from phosphonates and thiols through electrochemical reaction. The reactions were conducted without the addition of oxidant, transition-metal base, or base at room temperature. This system has a good substrate scope and functional group tolerance. Aryl and alkyl thiols worked well with phosphonates to afford the corresponding organothiophosphates in good yields.
|Appears in Collections:||化學系所|
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