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標題: Syntheses of Thioethers and Selenide Ethers from Anilines
作者: Yung-Jing Xue 
Yi-Chen Shieh 
Kai Du 
R. Sidick Basha 
Chin-Fa Lee 
Liang Li 
Bo-Hao Shih 
關鍵字: Chemical reactions;Ethers;Photocatalysts;Selenides;Thiols
In this study, a general procedure was proposed for synthesizing thioethers and selenide ethers from anilines under solvent-free and transition-metal-free conditions. Thioethers were formed when anilines reacted with thiols under blue light-emitting-diode (LED) irradiation at room temperature without a photocatalyst. When reactions were performed using anilines and diselenides, the corresponding selenide ethers were obtained with satisfactory to excellent yields. The reaction was performed under photocatalyst-free and solvent-free conditions without blue LEDs. The advantages of this system include convenient operations, mild reaction conditions, satisfactory functional group tolerance, and late-stage selenylation of drug molecules.
Appears in Collections:化學系所

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