Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/11204
標題: 電解沉積錫應用於薄膜鋰離子電池陽極之特性研究
Characterization of Electrolytic Sn Deposition for Thin-Film Lithium Ion Battery Anodes
作者: 賴建彰
Lai, Chien-Chang
關鍵字: tin;錫;anode;battery;陽極;鋰電池
出版社: 材料工程學系所
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摘要: 
本研究成功地在SnCl2及SnCl2、LiNO3混合水溶液中利用電化學方式在不銹鋼基材上分別製備Sn和Sn/Li2O薄膜,並利用XRD、SEM/EDS、以及ESCA來探討顯微結構、表面形貌以及成分分析,除此之外,也進行循環伏安(CV)和充放電測試對電化學性質討論。從電化學測試可證實Sn/Li2O薄膜比Sn擁有更好的循環性,且當充放電範圍為0.02 V - 0.9 V vs. Li/Li+ 及電流密度為800 μA/cm2時,循環性能得到很大的提高。利用定電位所沉積Sn/Li2O薄膜,經五十圈充放之後電容量仍有660 mAh/g,大於商用石墨電極之理論電容量(372 mAh/g)。

In this study, Sn and Sn/Li2O film has been successfully deposited on the stainless steel substrate in SnCl2 and SnCl2、LiNO3 mixed solutions by electrochemical method. The microstructure, morphology, and compositions of the materials were investigated by XRD, SEM/EDS, and ESCA. In addition, the electrochemical properties were investigated by CV analysis and charge/discharge cycle tests. Charge/discharge cycle tests demonstrated that Sn/Li2O film showed better cycle performance than pure Sn at the voltage range was 0.02 to 0.9 V and current density of 800 μA/cm2. The capacity of Sn/Li2O film by electrochemical method was still found 660 mAh/g after 50 cycle, and much higher than the capacity of the commercial graphite electrodes (372 mAh/g).
URI: http://hdl.handle.net/11455/11204
Appears in Collections:材料科學與工程學系

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